个人简历

1983年本科毕业于厦门大学化学系\r
1989年硕士研究生毕业于南京大学配位化学所、郑州大学和河南化学所（导师：金斗满研究员）\r
1996年博士研究生毕业于日本分子科学研究所（导师：高桥保 Tamotsu Takahashi 教授）； 曾先后在河南化学研究所金斗满研究室（1983年至1992年，实研、助研）、日本北海道大学触媒化学研究所高桥保研究室（1993年至1997年，博士研究生、博士后）、日本北海道大学药学部（1997年至1998年，助理教授）学习或工作\r
1998年北京大学化学学院副教授\r
1999年北京大学化学学院教授

研究领域

"""""本研究室目前研究兴趣集中在氮气的活化与转化，致力于实现温和条件下直接从氮气高效合成含氮有机化合物。研究内容涉及金属有机化学、配位化学、光化学、电化学、有机合成化学及催化"

近期论文

Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction Nan Li#, Botao Wu#, Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*Angew. Chem., Int. Ed. 2020, 59, 8868–8872.\r
\r
2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins Yu Zheng#, Chang-Su Cao#, Wangyang Ma#, Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2020, 142, 10705–10714.\r
\r
Rare-earth Metal Boroxide with Formal Triple Metal-Oxygen Orbital Interaction: Synthesis from B(C6F5)3·H2O and Radical-anion Ligated Rare-earth Metal Amides Haihan Yan#, Botao Wu#, Xiao-Kun Zhao, Chao Yu, Junnian Wei, Han-Shi Hu, Wen-Xiong Zhang*, and Zhenfeng Xi CCS Chem. 2020, 2, 2772–2781.\r
\r
Selective Reduction of 1,5-Diazacyclooctatetraenes: Synthesis and Structures of Aromatic Diazacyclooctatetraenyl Dianions and a 2,6-Bipyrrolinyl Dianionic Co(II) Complex Zhe Huang, Gengwen Tan, Chao Chen, Wen-Xiong Zhang, Xinping Wang and Zhenfeng Xi*Chem. Commun. 2019, 37, 71–75.\r
\r
Tetralithio Metalla-aromatics with Two Independent Perpendicular Dilithio Aromatic Rings Spiro-fused by One Mn Atom Yongliang Zhang, Junnian Wei, Miaomiao Zhu, Yue Chi, Wen-Xiong Zhang, Shengfa Ye*, and Zhenfeng Xi*Angew. Chem., Int. Ed. 2019, 58, 9625-9631.\r
\r
Isolation and Characterization of Four Phosphorus Cluster Anions P73-, P144-, P162- and P264- from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-Butadienes Shanshan Du, Jingyuan Hu, Zhengqi Chai, Wen-Xiong Zhang*, and Zhenfeng Xi Chin. J. Chem. 2019, 37, 71–75.\r
\r
Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand Shanshan Du, Zhengqi Chai, Jingyuan Hu, Wen-Xiong Zhang*, and Zhenfeng Xi Chin. J. Org. Chem. 2019, 39, 2338–2342.\r
\r
Synthesis and Characterization of Manganese(II) Complexes Supported by Cyclopentadienyl-Phosphine Ligand Gao-Xiang Wang#, Jianhao Yin#, Jiapeng Li#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*Inorg. Chem. Front. 2019, 6, 428-433. \r
\r
Indacyclopentadienes and Aromatic Indacyclopentadienyl Dianions: Synthesis and Characterization Yongliang Zhang, Zhenqiang Yang, Wen-Xiong Zhang*, and Zhenfeng Xi*Chem. Eur. J. 2019, 25, 4218-4224.\r
\r
Dilithio Spiro Zincacyclopentadienes and Dizinco[10]cycles: Synthesis and Structural Characterization Yongliang Zhang, Liang Liu, Tianyang Chen, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*Organometallics 2019, 38, 2174–2178.\r
\r
Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene Zhe Huang, Yongliang Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*Organometallics 2019, 38, 2807–2811.\r
\r
Alkaline-Earth Metallacyclic Complexes Bearing a Diborane-Bridged Tetraamide Ligand: Synthesis, Structure and Fluorescence Property Nan Li, Zifeng Zhao, Chao Yu, Botao Wu, Zuqiang Bian, Wen-Xiong Zhang*, and Zhenfeng Xi Dalton Trans. 2019, 48, 9067–9071\r
\r
Synthesis and Reactivity of Asymmetric Cr(I) Dinitrogen Complexes Supported by Cyclopentadienyl-Phosphine Ligands J.apeng Li#, Jianhao Yin#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi* Chem. Commun. 2019, 55, 9641-9644. \r
\r
Dinitrogen Functionalization Affording Chromium Hydrazido Complex J.anhao Yin#, Jiapeng Li#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi* J. Am. Chem. Soc. 2019, 141, 4241-4247. ( #Authors contributed equally.)\r
\r
Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds Shanshan Du#, Jimin Yang#, Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo*, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2019, 141, 6843–6847. ( #Authors contributed equally.)\r
\r
Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi* J. Am. Chem. Soc. 2019, 141, 8773–8777.\r
\r
Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2019, 141, 20547–20555.\r
\r
The Aromatic Dianion Metalloles Junnian Wei,* Wen-Xiong Zhang, and Zhenfeng Xi* Chem. Sci. 2018, 9, 560-568. (Perspective)\r
\r
Lewis Acid-Promoted Ring-Contraction of 2,4,6,8-Tetrasubstituted 1,5-Diazacyclooctatetraenes to 2,4,6-Trisubstituted Pyridines Zhe Huang, Wen-Xiong Zhang, and Zhenfeng Xi* Org. Lett. 2018, 20, 485-488.\r
\r
Rhodium-catalyzed intramolecular carbo-silylation of alkynes via C(sp3)-Si bond cleavage Qi Yang, Liang Liu, Yue Chi, Wei Hao, Wen-Xiong Zhang* and Zhenfeng Xi* Org. Chem. Front. 2018, 5, 860-863.\r
\r
Selective Transformation of Well-defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation Miaomiao Zhu, Liang Liu, Yongliang Zhang, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi* Chem. Eur. J. 2018, 24, 3186-3191. (Cover Paper)\r
\r
The Aromatic Dianion Metalloles Junnian Wei*, Wen-Xiong Zhang, and Zhenfeng Xi* Chem. Sci. 2018, 9, 560–568.\r
\r
Diversified Aggregation States of Phospholyl Lithiums Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi Organometallics 2018, 37, 2018–2022.\r
\r
Well-defined Styryl and Biphenyl Calcium Complexes from Dilithio Compounds and Calcium Iodide: Synthesis, Structure and Reactivity toward Nitrous Oxide Baosheng Wei, Wen-Xiong Zhang*, and Zhenfeng Xi*Dalton Trans. 2018, 47, 12540–12545.\r
\r
Magnesium Compounds: Generation and Synthetic Application Miaomiao Zhu, Liang Liu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi* Chem. Eur. J. 2018, 24, 19122–19135. (Invited Minireview)