郑丽敏
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""金属有机膦酸化学层状化合物是一类应用前景广阔的功能材料,在光、电、磁、催化、离子交换和传输及传感等方面都表现出优异的性能。石墨烯的发现更使传统层状化合物的研究得到了不可思议的复兴,相关研究已经拓展到其它许多无机层状化合物体系。由金属离子和有机配体构成的无机-有机杂化材料具有结构可以设计、功能易于调控等特点,探索新的无机-有机杂化低维材料并开发其功能性质及应用是目前该领域存在的关键科学问题之一。 作为一类重要的无机-有机杂化材料,金属有机膦酸化合物在过去二十多年中一直受到人们广泛的关注,已报道的这类化合物大都具有层状结构,热稳定性和水相稳定性较高,因而在探索无机-有机杂化低维材料方面很有潜力。我们的研究目标是组装结构新颖的金属有机膦酸化合物晶态材料和低维材料,深入研究其光、电、磁功能性质及其构效关系,为开发基于金属有机膦酸化合物并具有实际用途的功能材料提供基础。 研究兴趣: (1) 晶态和低维金属有机膦酸材料的组装; (2) 光磁双功能金属有机膦酸材料; (3) 清洁能源相关的金属有机膦酸质子导电材料; (4) 手性金属有机膦酸化合物及宏观螺旋材料; (5) 基于金属有机膦酸化合物的电催化材料。""""近期论文
1. Jia-Ge Jia,† Chen-Chen Zhao,† Song-Song Bao, Lan-Qing Wu, Ge-Hua Wen, Allan J. Jacobson, Jing Ma,* and Li-Min Zheng,* Layer or Tube? Uncovering Key Factors Determining the Rolling-up of Layered Coordination Polymers, J. Am. Chem. Soc. 2021, 143, 17587-17598. https://doi.org/10.1021/jacs.1c075172. Xin-Da Huang, Ge-Hua Wen, Song-Song Bao, Jia-Ge Jia and Li-Min Zheng,* Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties, Chem. Sci. 2021, 12, 929-937. https://doi.org/10.1039/d0sc04851h3. Guo-Guo Weng, Ben-Kun Hong, Song-Song Bao, Yujie Wen, Lan-Qing Wu, Xin-Da Huang, Jia-Ge Jia, Ge-Hua Wen, Shu-Hua Li, Luming Peng and Li-Min Zheng,* From helices to superhelices: hierarchical assembly of homochiral van der Waals 1D coordination polymers, Chem. Sci. 2021, 12, 12619-12630. https://doi.org/10.1039/d1sc01913a4. Kun Zhang, Ge-Hua Wen, Xiao-Jing Yang, Dae-Woon Lim, Song-Song Bao, Masaki Donoshita, Lan-Qing Wu, Hiroshi Kitagawa,* and Li-Min Zheng,* Anhydrous Superprotonic Conductivity of a Uranyl-Based MOF from Ambient Temperature to 110 °C, ACS Mater. Lett. 2021, 3, 744-751. https://doi.org/10.1021/acsmaterialslett.1c001765. Qian Zou, Tao Shang, Xin-Da Huang, Qing-Qing Guo, Jia-Ge Jia, Song-Song Bao,* Yi-Quan Zhang* and Li-Min Zheng,* Dysprosium-dianthracene framework showing thermo-responsive magnetic and luminescence properties, J. Mater. Chem. C 2021, 9, 10749-10758. https://doi.org/10.1039/d1tc01027a6. Qian Zou,† Jing-Cui Liu,† Xin-Da Huang, Song-Song Bao, Li-Min Zheng,* Thermo-induced structural transformation with synergistic optical and magnetic changes in ytterbium and erbium complexes, Chin. Chem. Lett. 2021, 32, 1519-1522. https://doi.org/10.1016/j.cclet.2020.10.0197. Ming-Feng Qin,† Qiao-Qiao Mu,† Song-Song Bao, Xu Liang, Yang Peng,* and Li-Min Zheng,* Chemically Exfoliated Semiconducting Bimetallic Porphyrinylphosphonate Metal-Organic Layers for Photocatalytic CO2 Reduction under Visible Light, ACS Appl. Energy Mater. 2021, 4, 4319-4326. https://doi.org/10.1021/acsaem.1c007658. Lan-Qing Wu, Yan Xu, Ting Hou, Jia-Ge Jia, Xin-Da Huang, Guo-Guo Weng, Song-Song Bao,* and Li-Min Zheng,* Controllable Macroscopic Chirality of Coordination Polymers through pH and Anion-Mediated Weak Interactions, Chem. Eur. J. 2021, 27, 16722-16734. https://doi.org/10.1002/chem.2021029549. Guo-Guo Weng,† Xin-Da Huang,† Rui Hu, Song-Song Bao, Qian Zou, Ge-Hua Wen, Yi-Quan Zhang,* and Li-Min Zheng,* Homochiral Dysprosium Phosphonate Nanowires: Morphology Control and Magnetic Dynamics, Chem. Asian J. 2021, 16, 2648-2658. https://doi.org/10.1002/asia.20210067010. Qian Zou, Song-Song Bao, Xin-Da Huang, Ge-Hua Wen, Jia-Ge Jia, Lan-Qing Wu, and Li-Min Zheng,* Cobalt(II)-dianthracene Frameworks: Assembly, Exfoliation and Properties, Chem. Asian J. 2021, 16, 1456-1465. https://doi.org/10.1002/asia.20210028311. Ge-Hua Wen, Xiu-Mei Chen, Kui Xu, Xiaoji Xie, Song-Song Bao* and Li-Min Zheng,* Uranyl phosphonates: crystalline materials and nanosheets for temperature sensing, Dalton Trans. 2021, 50, 17129-17139. https://doi.org/10.1039/d1dt02977k12. Ge-Hua Wen, Qian Zou, Xin-Da Huang, Kun Zhang, Song-Song Bao, Li-Min Zheng,* Heterometallic uranyl-organic frameworks incorporating manganese and copper: Structures, ammonia sorption and magnetic properties, Polyhedron 2021, 205, 115327. https://doi.org/10.1016/j.poly.2021.11532713. Jing-Cui Liu, Qian Zou, Xin-Da Huang, Song-Song Bao, and Li-Min Zheng,* Dysprosium Coordination Polymer Incorporating Dianthracene: Thermo-induced Phase Transition Accompanied with Magnetic and Optical Changes, Eur. J. Inorg. Chem. 2021, 2021, 1565-1570. https://doi.org/10.1002/ejic.20210013814. Guo-Bin Sun, Xin-Da Huang, Tao Shang, Shuo Yan, Song-Song Bao, Xiao-Mei Lu, Yi-Quan Zhang,* and Li-Min Zheng,* Polar Lanthanide Anthracene Complexes Exhibiting Magnetic, Luminescent and Dielectric Properties, Eur. J. Inorg. Chem. 2021, 2021, 4207-4215. https://doi.org/10.1002/ejic.20210053815. Wen Yan, Kun Fan, Li-Min Zheng,* and Zhong Jin,* Cluster-Bridging-Coordinated Bimetallic Metal-Organic Framework as High-Performance Anode Material for Lithium-Ion Storage, Small Struct. 2021, 2100122. https://doi.org/10.1002/sstr.202100122标签: 南京大学 配位化学国家重点实验室
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