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曾德文
2023-05-18 12:45
  • 曾德文
  • 曾德文 - 教授,博导-中南大学-化学化工学院-个人资料

近期热点

资料介绍

个人简历


曾德文:男,1992年硕士毕业于中南大学有色冶金系并留校任教。1999年5月至2002年8月在德国佛赖贝格工业大学无机化学研究所学习和工作,完成了德国国家科学基金(DFG)等多项课题,获理学博士学位。然后受德国教育与科技部(BMBF)资助在佛赖贝格工业大学能源工程与化工研究所进行博士后工作,2003年11月回国。现为中南大学化学化工学院“升华学者”特聘教授,博士生导师,国际纯粹与应用化学联盟(IUPAC)溶解度平衡数据委员会委员 教育经历 [1] 1999.5-2003.7 佛莱贝格矿业大学 | 无机化学 | 博士学位 | 博士研究生毕业 [2] 1989.9-1992.5 中南工业大学 | 有色冶金 | 硕士学位 | 硕士研究生毕业 [3] 1985.9-1989.7 中南工业大学 | 有色冶金 | 学士学位 | 大学本科毕业

研究领域


无机盐溶液热力学与相平衡,无机储能材料设计。"1. 电解质水溶液微观结构研究
(液-固、液-气、液-液)相平衡宏观性质是其微观性质的反映。理解宏观性质得从微观性质入手。例如:1)同为碱土金属的硫酸盐,为何硫酸钙的溶解度只是硫酸镁溶解度的百分之一?2)为什么溶液中NH4F的存在会使MgF2的溶解度降低百倍,而MgCl2的存在却使MgF2的溶解度增大百倍?3)加入把固体KCl(RbCl、CsCl)加到高浓度的CuCl2(或CaCl2、ZnCl2)水溶液中,溶液中水的活度却反而升高?4)为何很多的物质(如水与煤油)只是在接近纯物质的两端有限互溶?5)为何有些电解质溶液的结晶会存在强烈的过冷(过冷度超过60度),而另一些却不会?…对相关溶液结构的研究,有助于加深我们对这些问题的本质认识

近期论文


D. Zeng*, Z. Wu, Y. Yao, H. Han, Isopiestic Determination of water activity on the system LiNO3+KNO3+H2O at 273.1 and 298.1 K, J Solution Chem., 39 (2010) 1360-1376.(Sci)
L. Guo, B. Sun, D. Zeng*, Y. Yao, H. Han, Isopiestic Measurement and Solubility Evaluation of the Ternary System LiCl−SrCl2−H2O at 298.15 K, J. Chem. Eng. Data, 57 (2012) 817-827.(Sci)
L. Guo, D. Zeng*, Y. Yao, H. Han, Isopiestic measurement and solubility evaluation of the ternary system (CaCl2+SrCl2+H2O) at T=298.15 K, J. Chem. Thermodynamics, 63 (2013) 60-66.(Sci)
H. Yang, D. Zeng, W. Voigt, G. Hefter, Sh. Liu, Q. Chen, Isopiestic Measurements on Aqueous Solutions of Heavy Metal Sulfates: MSO4+H2O(M=Mn,Co,Ni,Cu,Zn). 1. T=323.15 K. J. Chem. Eng. Data, 59(2014) 97-102.
W. Voigt, K. Dittrich, D. Zeng, Ion coordination and thermodynamic modelling of molten salt hydrate mixtures, in the book: “Thermodynamic Properties of Complex Fluid Mixtures”, Wiley-VCH Verlag GmbH & Co. KGaA, ISBN 3-527-27770-6, 2004, p241-267.
F. Xia, H. Yi, D. Zeng*, Hydrates of Copper Dichloride in Aqueous Solution: A Density Functional Theory and Polarized Continuum Model Investigation, Polarized Continuum Model Investigation, J. Phys. Chem. A 113 (2009) 14029-14038. (Sci)
F. Xia, H. Yi*, D. Zeng*, Hydrates of Cu2+ and CuCl+ in dilute aqueous solution: a density functional theory and polarized continuum model investigation, J. Phys. Chem. A 114 (2010) 8406-8416. (Sci)
H. Yi*, F. Xia, Q. Zhou, D. Zeng*, [CuCl3]- and [CuCl4]2- Hydration in Concentrated Aqueous Solution: a density functional theory and ab inition study, J. Phys. Chem., 115 (2011) 4416-4426.(Sci)
F.F. Xia, D. Zeng*, H.B. Yi, Ch.H. Fang, Direct Contact versus Solvent-shared Ion Pairs in Saturated NiCl2 Aqueous Solution: A DFT, CPMD, and EXAFS Investigation, J. Phys. Chem. A., 117 (2013) 8468-8476.
N. Zhang, Q. Zhou, X. Yin, D. Zeng, Trace amounts of aqueous opper(II) chloride complexes in hypersaline solutions: spectrophotometric and thermodynamic studies. J. Solution Chem. 43 (2014) 326-339.
N. Zhang, D. Zeng,* G. Hefter, Q. Chen, Chemical speciation in concentrated aqueous solutions of CuCl2 using thin-film UV–visible spectroscopy combined with DFT calculations, J. Molecular Liquids, 198 (2014) 200-203.
尹霞,万艳鹏,李碧海,曾德文*, 高溶解性盐水体系热力学模型预测能力的比较研究I: 二元体系,化学学报,66 (2008) 1815-1826. (Sci)
Q. Zhou, D. Zeng*, W. Voigt, Thermodynamic modeling of salt-water systems up to saturation concentrations based on solute speciation: CuCl2–MCln–H2O at 298 K (M = Li, Mg, Ca), Fluid Phase Equilibria, 322-323 (2012) 30-40.(Sci)
W.Voigt,; D. Zeng, Solid-liquid equilibria in mixtures of molten salt hydrates for the design of heat storage materials, Pure and Applied Chemistry, 74 (2002) 1909-1920. (Sci)
W. Voigt, K. Rudolf, D. Zeng, High-Throughput-Techniken in der Kristallisationsforschung, Moderne Methoden zur Untersuchung von Löse- und Kristallisations prozessen, Freiberg Forschungshefte, (2002) 169-182.
D. Zeng, W. Voigt, Phase diagram calculation of molten hydrates using the modified BET equation, C ALPHAD, 27 (2003) 243-251. (Sci, Ei)
D. Zeng, C. Fang, S. Chen, Phase diagram prediction of the heat storage systems Mn(NO3)2- M(NO3)n-H2O (M=Ca, Mg and Li) with modified BET-Model, Trans. Nonferrous Met. Soc. China, 14 (2004) 1192-1198. (Sci, Ei)
尹霞,吴玉双,李琴香,曾德文*, 王成. LiNO3-KNO3-H2O三元体系相平衡研究. 无机化学学报,26(1) (2010) 45-48. (Sci)
B. Li, D. Zeng*, X. Yin, Q. Chen, Theoretical prediction and experimental determination of room-temperature phase change materials using hydrated salts as agents. J. Therm. Anal. Calorim. 100 (2010) 685-693. (Sci)
X. Yin, Q. Chen, D. Zeng*, W. Wang, Phase Diagram of the System KNO3 + LiNO3 + Mg(NO3)2 + H2O, CALPHAD, 35 (2011) 463-472.(Sci)
O. Dong, D. Zeng*, H. Zhou, H. Han, X. Yin, Y. DU. Phase change materials in the ternary system NH4Cl-CaCl2+H2O, CALPHAD, 35 (2011) 269-275.(Sci)
尹霞,陈启元,王文磊,曾德文*,四元体系LiNO3-Mg(NO3)2-NH4NO3-H2O相图预测及相关相变储能材料的研究,无机化学学报,28(2012) 1873-1877. (Sci)
尹霞,陈启元,曾德文*,杜勇,用于室温相变储能材料的NaNO3-LiNO3-KNO3-H2O体系相图预测,中国有色金属学报,22 (2012)2875-2881. (Ei)
X. Yin, X. Yu, X. Wu, X. Fu, H. Wu, D. Zeng, Solubility Prediction and Measurement of the System KNO3−LiNO3−NaNO3−H2O, J. Chem. Eng. Data, 58 (2013) 1839-1844. (Sci)

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