个人简历

1988年9月─1992年7月 湖南师范大学化学系，理学学士\r
1992年7月─1997年7月 湖南省邵阳师范高等专科学校，讲师\r
1997年8月─2000年7月 上海化工研究院，硕士\r
2000年8月─2003年7月 中科院上海有机所，理学博士\r
2003年8月─2005年7月 美国University of Idaho，博士后\r
2005年9月─ 中科院上海有机所，研究员，博士生导师

研究领域

"""""含氟有机盐 发展新的有机盐及其合成方法，研究其催化、反应性能以及理化特性；发展新的氟化试剂，发现新的氟化反应；探索有机盐在电解质、光学材料等领域的应用\r
熔盐化学 研究金属氟化物的合成以及相应熔盐的制备，探索氟化盐及熔盐中杂质的存在形式与迁移规律，发展氟化熔盐的纯化方法\r
稀土萃取 探索稀土金属离子的结构化学特征和配位化学反应规律，阐明稀土萃取剂的分子结构与萃取性能之间的关系，发展碳磷键的合成方法学\r
高张力含氟小分子 通过考察含氟卡宾与双键、叁键的反应，探索高张力含氟小分子的合成与反应性能，发展有机氟化物的合成方法学\r
含氟卟啉化学 研究含氟卟啉的合成与反应规律，探索其在催化和材料方面的应用"

近期论文

Xiao-Yun Deng , Jin-Hong Lin , Ji-Chang Xiao , One-pot synthesis of gem-difluorostyrenes from benzyl bromide via olefination of phosphonium ylide with difluorocarbene , Journal of Fluorine Chemistry , Available online 11 June 2015 , DOI: 10.1016/j.jfluchem.2015.06.009\r
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Xiao-Yun Deng , Jin-Hong Lin , Jian Zheng and Ji-Chang Xiao , Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation , Chem. Commun , 2015 , 51(42) , 8805-8808 , DOI: 10.1039/c5cc02736e\r
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Jian Zheng , Jin-Hong Lin , Xiao-Yun Deng and Ji-Chang Xiao , 1,8-Diazabicyclo[5.4.0] undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation , Organic Letters , 2015 , 17(3) , 532-535 , DOI: 10.1021/ol503548s\r
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Yaya Duan , Bin Zhou , Jin-Hong Lin , Ji-Chang Xiao , Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation Chem. Commun , 2015 , 51(66) ,13127-13130 ,DOI: 10.1039/c5cc04991a \r
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Wang Shi-Meng , Han Jia-Bin , Zhang Cheng-Pan , Qin Hua-Li , Xiao Ji-Chang , An overview of reductive trifluoromethylatio reactions using electrophilic ‘+CF3’ reagents , Tetrahedron, Available online 20 June 2015 , DOI:10.1016/j.tet.2015.06.056\r
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Wu Hao , Xiao Zhiwei , Wu Junhui , Guo Yong , Xiao Ji-Chang , Liu Chao , Chen Qing Yun, Direct trifluoromethylthiolation of unactivated C(sp(3)​)​-​H using silver(I) trifluoromethanethiolate and potassium persulfate , Angewandte Chemie , 2015 , 54(13) , 4070-4074 , DOI: 10.1002/anie.201411953 \r
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Shen Qian , Huang Yan-Gen , Liu Chao , Xiao Ji-Chang , Chen Qing-Yun , Guo Yong , Review of recent advances in C-​F bond activation of aliphatic fluorides , Journal of Fluorine Chemistry , Available online 13 July 2015 , DOI:10.1016/j.jfluchem.2015.07.007\r
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Liu Hao , Yu Jing , Li Xinyu , Yan Rui , Xiao Ji-Chang , Hong Ran, Stereoselectivity in N-​Iminium Ion Cyclization: Development of an Efficient Synthesis of (±)​-​Cephalotaxine, Organic Letters , 2015, DOI: 10.1021/acs.orglett.5b02106\r
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Jian Zheng , Lu Wang , Jin-Hong Lin , Ji-Chang Xiao , Steven H. Liang , Difluorocarbene-Derived Trifluoromethylthiolation and [18F] Trifluoromethylthiolation of Aliphatic Electrophiles , Angewandte Chemie , 2015 , 54 , 1-6 , DOI: 10.1002/anie.201505446\r
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44. He Zhang , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Rh-catalyzed allylic C-F bond activation : the stereoselective synthesis of trisubstituted monofluoroalkenes and a mechanism study , Org. Biomol. Chem , 2014 , 12 , 581-588 , DOI: 10.1039/C3OB42038H\r
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Tang-Po Yang , Qiang Li , Jin-Hong Lin , Ji-Chang Xiao , Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocy clopropyl ketones , Chemical Communications , 2014 , 50(9) , 1077-1079 , DOI: 10.1039/c3cc47879c\r
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Xiao-Ping Wang , Jin-Hong Lin , Ji-Chang Xiao , Xing Zheng , Decarboxylative Julia-Kocienski gem-Difluoro-Olefination of 2-Pyridinyl Sulfonyldifluoroacetate , European Journal of Organic Chemistry , 2014 , 2014(5), 928-932 , DOI: 10.1002/ejoc.201301654\r
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Qiang Li , Jin-Hong Lin , Zu-Yong Deng , Jian Zheng , Ji Cai , Ji-Chang Xiao , Wittig gem-difluoroolefination of aldehydes with difluoromethyltriphenyphosphonium bromide , Journal of Fluorine Chemistry , 2014 , 163 , 38-41, DOI: 10.1016/j.jfluchem.2014.04.011\r
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Yun-Long Ji , Jun-Jie Kong , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes , Organic ＆Biomolecular Chemistry , 2014 , 12(18) , 2903-2906 , DOI: 10.1039/C3OB42575D\r
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Wei-Peng Gu , Jin-Hong Lin , Ji-Chang Xiao , Direct N-gem-difluorocyclopropylation of nitro-heterocycles by utilizing gem-difluorocyclopropylation tosylate , Chinese Chemical Letters , 2014 , 25(1) , 24-28, DOI: 10.1016/j.cclet.2013.11.027\r
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Dong-Fang Jiang , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes , European Journal of Organic Chemistry , 2014(28), 6303-6309, DOI: 10.1002/ejoc.201402820\r
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Shuai Zhao , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , B-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties , Synthesis , 2014 , 46(12) , 1674-1688. DOI: 10.1055/S-0033-1341055.\r
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Yun-Long Ji , Jin-Hong Lin , Ji-Chang Xiao and Yu-Cheng Gu , Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes , Organic Chemistry Frontiers , 2014 , 1(11) , 1280-1284. DOI: 10.1039/c4qo00240g\r
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Cheng-Pan Zhang , Qing-Yun Chen , Yong Guo , Ji-Chang Xiao , Yu-Cheng Gu , Difluoromethylation and trifluoromethylation reagents derived from terrafluoroethane B-sultone: Synthesis , reactivety and applications , Coordination Chemistry Reviews , 2014 , 261 , 28-72. DOI: 10.1016/j.ccr.2013.11.010\r
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Shuai Zhao , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , Oxidative coupling of benzylamines to imines by molecular oxygen catalyzed by cobalt(Ⅱ) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin , The Journal of Organic Chemistry , 2014 , 79(18) , 8926-8931. DOI: 10.1021/jo5017212\r
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Jin-Hong Lin , Ji-Chang Xiao , Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis , Tetrahedron Letters , 2014 , 55(45) , 6147-6155. DOI: 10.1016/j.tetlet.2014.09031\r
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Yun-Long Ji , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Stereoselective Synthesis of α-Trifluoromethyl Enones by AuⅠ/CuⅠ-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates , European Journal of Organic Chemistry , 2014(35) , 7948-7954 . DOI: 10.1002/ejoc.201403115\r