个人简历

2002年本科毕业于武汉大学环境化学系；2007年获中科院化学所物理化学专业博士学位。2007至2013年先后在加拿大新布伦瑞克大学(The University of New Brunswick)和德国乌帕塔尔大学(Bergische Universitaet Wuppertal)从事博士后研究工作，得到德国洪堡基金会AvH (2008-2010年)和德国自然科学基金会DFG (2011-2013年)独立项目资助。2013年加盟苏州大学材料与化学化工学部，现任化学院物理化学系特聘教授，博士生导师。2014年获国家自然科学基金优秀青年基金。\r
\r
学习与工作经历\r
2013 苏州大学材料与化学化工学部, 特聘教授、博士生导师\r
2010 德国Wuppertal大学无机化学系, 德国科学基金会DFG项目负责人\r
2008 德国Wuppertal大学无机化学系, 洪堡访问学者 指导教授：Helge Willner\r
2007 加拿大NewBrunswick大学化学系，博士后 指导教授：Jack Passmore\r
2007 中国科学院北京化学研究所，分子动态与稳态结构国家重点实验室，理学博士 指导教授：王殿勋\r
2002 武汉大学，化学与环境科学学院，环境化学专业，理学学士\r
2013 Professor, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China\r
2010 DFG project scientist, Bergische Universitaet,Wuppertal, Germany\r
2008 Alexander von Humboldt Fellow, BergischeUniversitaet, Wuppertal, Germany\r
2007 Postdoc, University of New Brunswick, Fredericton,Canada\r
2007 PhD,Institute of Chemistry, Chinese Academy of Sciences, Beijing, China\r
2002 Bachelor, Departmentof Resource and Environmental Science, Wuhan University, China

研究领域

"""""新颖功能小分子的结构与反应\r
关键反应中间体的光谱探测\r
反应机理与相关理论\r
发展新光谱探测技术"

近期论文

Wu, Z.; Chen, C. Y.; Liu, J.; Lu, Y.; Xu, J.; Liu, X. Y.; Cui, G. L.; Tralbelsi, T.; Francisco, J. S.; Zeng. X. Q. The Caged Nitric Oxide–Thiyl Radical Pairs. Submitted. 2018.\r
\r
Chu. X. X.; Song, C.; Yang, Y.; Zeng. X. Q. Oxidation of phosphinidene oxide: Formation of dioxaphosphirane oxide with oxygen scrambling. Chem. Commun. 2018, DOI: 10.1039/C8CC08945K.\r
\r
Dong, X. L.; Deng, G. H.; Xu, J.; Li, H. M.; Zeng. X. Q. Decomposition of Sulfonyl Azide Isocyanate and Sulfonyl Diazide: The Oxygen-Shifted Curtius Rearrangement via Sulfonyl Nitrenes. J. Phys. Chem. A 2018, 122, 8511–8519.\r
\r
Lu, Y.; Li, H, M.; Wan. H. B.; Liu, Q.; Deng, G. H.; Zeng. X. Q. Flash vacuum pyrolysis of sulfamoyl azides and chlorides: Facile gas-phase generation of transient N-sulfonylamines. J. Anal. Appl. Pyrol. 2018, 134, 476-483.\r
\r
Liu, Q.; Wan. H. B.; Lu, Y.; Lu, B.; Zeng. X. Q. Photodecomposition of 1H‐Pyrrole Carbonyl Azides: Direct Observation of Singlet 1H‐Pyrrole Carbonyl Nitrenes and Triplet 1H‐3‐Pyrrylnitrene. Eur. J. Org. Chem. 2018, doi.org/10.1002/ejoc.201800830.\r
\r
Chu, X. X.; Yang, Y.; Lu, B.; Wu, Z.; Qian, W. Y.; Song, C.; Xu, X. F.; Abe, M.; Zeng, X. Q. Methoxyphosphinidene and Isomeric Methylphosphinidene Oxide. J. Am. Chem. Soc. 2018, 140, 13604–13608.\r
\r
Wu, Z.; Song, C.; Liu, J.; Lu, B.; Lu, Y.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Photochemistry of OPN: Formation of Cyclic PON and Reversible Combination with Carbon Monoxide. Chem. Eur. J. 2018, 24, 14627-14630.\r
\r
Xu, J.; Wu, Z.; Wan, H. B.; Deng, G. H.; Lu, B.; Eckhardt, A. K.; Schreiner, P. R.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Phenylsulfinyl Radical: Gas-phase Generation, Photoisomerization, and Oxidation. J. Am. Chem. Soc. 2018, 140, 9972–9978.\r
\r
Lu, Y.; Li, H. M.; Abe, M.; Begue, D.; Wan, H. B.; Deng, G. H.; Xu, J.; Liu, K.; Zeng, X. Q. Sulfamoyl Nitrenes: Singlet or Triplet Ground State?. Chem. Common. 2018, 54, 6136-6139.\r
\r
Dong, X. L.; Deng, G. H.; Xu. J. Lu, B.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Spectroscopic Identification of H2NSO and syn- and anti-HNSOH Radicals. Angew. Chem. Int. Ed. 2018, 57, 7513-7517.\r
\r
Wu. Z.; Wan, H. B.; Xu. J. Lu, B.; Eckhardt, A. K.; Schreiner, P. R.; Xie, C. J.; Guo, H.; Zeng, X. Q. The Near-UV Absorber OSSO and Its Isomers. Chem. Common.. 2018, 54, 4517-4520.\r
\r
Wu. Z.; Feng, R. J.; Xu. J.; Lu. Y.; Lu, B.; Yang, T.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Photoinduced Sulfur-Nitrogen Bond Rotation and Thermal Nitrogen Inversion in Heterocumulene OSNSO. J. Am. Chem. Soc. 2018, 140, 1231–1234.\r
\r
Feng, R. J.; Lu. Y.; Deng, G. H..; Xu. J.; Wu. Z.; Li, H. M.; Liu. Q.; Norito Kadowaki; Manabu Abe; Zeng. X. Q. Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene. J. Am. Chem. Soc. 2018, 140, 10–13.\r
\r
Wu. Z.; Lu. B.; Feng, R. J.; Xu. J.; Lu. Y.; Wan H. B.; André K. Eckhardt; Peter R. Schreiner; Changjian Xie; Hua Guo; Xiaoqing Zeng Capture of SO3 isomers in the oxidation of sulfur monoxide with molecular oxygen. Chem. Common. 2018, 54, 1690–1693.\r
\r
Feng, R. J.; Wu, Z.; Zeng, X. Q. Synthesis, conformation, and photochemistry of difluoroacetyl isocyanate CF2HC(O)NCO and isothiocyanate CF2HC(O)NCS. J. M. S. DOI: 10.1016/j.molstruc.2017.10.109.\r
\r
Wan, H. B.; Xu, J.; Liu, Q.; Li, H. M.; Lu, Y.; Abe, M.; Zeng, X. Q.; Contrasting Photolyticand Thermal Decompositionof Phenyl Azidoformate: the Curtius Rearrangement VersusIntramolecular C-H Amination. J. Phys. Chem. A. DOI:10.1021/acs.jpca.7b07969.\r
\r
Wu, Z.; Xu, J.; Deng, G. H.; Chu, X. X.; Sokolenko, L.; Trabelsi, T.; Francisco, J. S.; Eckhardt, A. K.; Zeng, X. Q.; Schreiner, P. R. The Trifluoromethyl Sulfinyl And Oxathiyl Radicals. Chem. -Eur J. 2018, 24, 1505–1508 .\r
\r
Wu, Z.; Xu, J.; Sokolenko, L.; Yagupolskii, Y. L.; Feng, R. J.; Liu, Q.; Lu, Y.; Zhao, L. L.; Fernandez, I.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Parent Thioketene S-Oxide H2CCSO: Gas-Phase Generation, Structure, and Bonding Analysis. Chem. –Eur. J. 2017, 23, 16566–16573 .\r
\r
Wu, Z.; Feng, R. J.; Li, H. M.; Xu, J.; Deng, G. H.;Abe, M.;Bégué, D.; Liu, K.; Zeng, X. Q. Fast Heavy-Atom: Tunneling in Trifluoroacetyl Nitrene. Angew. Chem. Int. Ed. 2017, DOI: 10.1002/ange.201710307.\r
\r
Wan, H. B.; Li, H. M.; Xu, J.; Wu, Z.; Liu, Q. F.; Chu, X. X.; Abe, M.; Bégué, D.; Zeng, X. Q.N-Methylcarbamoyl Azide: Spectroscopy, X-ray Structure and Decomposition via Methylcarbamoyl Nitrene. Org. Chem. Front. 2017, 4, 1839–1848.