个人简历

曹建，博士，副研究员，硕士生导师。2010年6月于浙江大学获博士学位；2010年7月加入杭州师范大学有机硅化学及材料技术教育部重点实验室，目前主要从事有机合成方法学和有机硅化学的基础和应用研究。先后主持和参与了国家自然科学基金、浙江省自然科学基金和杭州市科技项目。已在Angew. Chem. Int. Ed.; Coord. Chem. Rev.; Chem. Commun.; Org. Lett.; Adv. Synth. Catal.等权威期刊上发表学术论文30余篇；其中多篇论文入选Synfacts。指导研究生多次获得国家奖学金和经亨颐奖学金。\r
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主要学习经历\r
2005.9~2010.6 浙江大学，博士（导师：黄宪院士）\r
2017.10~2018.10 瑞士洛桑联邦理工学院，访问学者（合作教授：祝介平教授）

研究领域

"""""1. 过渡金属催化的不对称合成方法研究\r
2. 小环化合物的合成和反应研究\r
3. 有机硅化合物的合成和反应研究"

近期论文

Yu-Li Sun, Xing-Ben Wang, Feng-Na Sun, Qian-Qian Chen, Jian Cao,* Zheng Xu,* and Li-Wen Xu*, Enantioselective Cross-Exchange between C−I and C−C σ‑Bonds. Angew. Chem. Int. Ed. 2019, 58, 6747.\r
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Jian Cao,* Ling Chen, Feng-Na Sun, Yu-Li Sun, Ke-Zhi Jiang, Ke-Fang Yang, Zheng Xu, Li-Wen Xu*, Pd-Catalyzed Enantioselective Ring-Opening/Cross-Coupling and Cyclopropanation of Cyclobutanones. Angew. Chem. Int. Ed. 2019, 58, 897. (Highlighted by Synfacts 2019, 15, 281)\r
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Yu-Li Sun, Ling Chen, Jian Cao,* Feng-Na Sun, Zheng Xu, Zhan-Jiang Zheng, Yu-Ming Cui, Li-Wen Xu*. Lewis Acid-Catalyzed Yne-Carbonyl Metathesis of Ynamides and Cyclobutanones: Facile Synthesis of Functionalized Alkylidenecyclobutanes. Asian J. Org. Chem. 2018, 7, 374.\r
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Ling Chen, Feng-Na Sun, Yu-Li Sun, Zheng Xu, Zhan-Jiang Zheng, Yu-Ming Cui, Jian Cao,* Li-Wen Xu*. Palladium-Catalyzed Ring-Opening of 2-Alkylidenecyclobutanols: Stereoselective Synthesis of γ,δ-Unsaturated Ketones by C-C Bond Cleavage. Adv. Synth. Catal. 2018, 360, 411.\r
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ian Cao,* Zhan-Jiang Zheng, Zheng Xu, Li-Wen Xu*. Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source. Coord. Chem. Rev. 2017, 336, 43.\r
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Ling Chen, Yu-Ming Cui, Zheng Xu, Jian Cao,* Zhan-Jiang Zheng, Li-Wen Xu*. An efficient approach toward formation of polycyclic coumarin derivatives via carbocation-initiated [4 + 2] cycloaddition and atom-economic photo-irradiated cyclization. Chem. Commun. 2016, 52, 11131.\r
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Ling Chen, Jian Cao,* Zheng Xu, Zhan-Jiang Zheng, Yu-Ming Cui, Li-Wen Xu*. Lewis acid catalyzed [2 + 2] cycloaddition of ynamides and propargyl silyl ethers: synthesis of alkylidenecyclobutenones and their reactivity in ring-opening and ring expansion. Chem. Commun. 2016, 52, 9574.\r
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Ling Chen, Lian Yu, Yuan Deng, Zhan-Jiang Zheng, Zheng Xu, Jian Cao,* Li-Wen Xu*. C-H functionalization/C-O bond cleavage of benzyl silyl ethers with ynamides for the chemoselective synthesis of skeletally diverse compounds. Adv. Synth. Catal. 2016, 358, 480.\r
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Ling Chen, Lian Yu, Yuan Deng, Yuming Cui, Gaofeng Bian, Jian Cao*. Synthesis of α-haloenamides via zinc halide mediated direct addition of benzhydryl halides to ynamides. Org. Biomol. Chem. 2016, 14, 564.\r
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Lian Yu, Yuan Deng, Jian Cao*. Regioselective synthesis of highly substituted imidazoles via the sequential reaction of allenyl sulfonamides and amines. J. Org. Chem. 2015, 80, 4729.\r
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Lian Yu, Yuan Deng, Jian Cao*. Synthesis of ketenaminals via catalyst-free hydroamination of ynamides and diphenylsulfonimide. Synthesis 2015, 47, 783.\r
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Lian Yu, Jian Cao*. Synthesis of α,β-unsaturated amides and iminocoumarins from N,N-disulfonyl ynamides with aldehydes via the ketenimine intermediate. Org. Biomol. Chem. 2014, 12, 3986.\r
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Yulong Kong, Lian Yu, Yuming Cui, Jian Cao*. Synthesis of N-sulfonylamidines by catalyst-free hydroamination of ynamides and amines. Synthesis 2014, 46, 183.\r
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Yulong Kong, Kezhi Jiang, Jian Cao,* Lingzi Fu, Lian Yu, Guoqiao Lai, Yuming Cui, Ziqiang Hu, Guanhai Wang. Synthesis of 3-alkyl- or 3-allenyl-2-amidobenzofurans via electrophilic cyclization of o-anisole-substituted ynamides with carbocations. Org. Lett. 2013, 15, 422.\r
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Yulong Kong, Lian Yu, Lingzi Fu, Jian Cao,* Guoqiao Lai, Yuming Cui, Ziqiang Hu, Guanhai Wang. Electrophilic cyclization of o-anisole- and o-thioanisole-substituted ynamides: synthesis of 2-amidobenzofurans and 2-amidobenzothiophenes. Synthesis 2013, 45, 1975.\r
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Jian Cao,* Yongping Xu, Yulong Kong, Yuming Cui, Ziqiang Hu, Guanhai Wang, Yuan Deng, Guoqiao Lai*. Synthesis of δ-carbolines via a Pd-catalyzed sequential reaction from 2-iodoanilines and N-tosyl-enynamines. Org. Lett. 2012, 14, 38.\r
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Jian Cao,* Yulong Kong, Yuan Deng, Guoqiao Lai,* Yuming Cui, Ziqiang Hu, Guanhai Wang. Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids. Org. Biomol. Chem. 2012, 10, 9556.