江智勇
近期热点
资料介绍
个人简历
江智勇,男,学院院长。入选国家杰青、百千万人才工程国家级人选,国务院政府特贴专家,教育部新世纪优秀人才支持计划,国家“有突出贡献中青年专家”,河南省特聘教授,河南省创新型科技团队及省高校科技创新团队(牵头人),河南省学术技术带头人,第四届中国青年科技工作者协会理事,河南省高校青年骨干教师,中国化学会会员,河南省化学会常务理事,国际期刊Mini-Rev. Med. Chem.编委,河南省青年科技工作者协会常务理事。教育经历:1992.09-1996.06 浙江大学化学系,化学专业,理学学士;1999.09-2004.01 浙江大学化学系,有机化学专业,理学博士;工作经历:2004.02—2005.04,香港浸会大学化学系,博士后,合作导师:Wing-Hong Chan教授;2005.08—2009.08,新加坡国立大学化学系,博士后,合作导师:Choon-Hong Tan教授;2009.08—2018.08,河南大学河南省天然药物与免疫工程重点实验室教授,博士生导师,副主任;2013.04—2013.10,新加坡南洋理工大学化学与生物化学学院,高级研究员;2018.08—至今,河南师范大学化学化工学院教授,博士生导师,院长;近年来主持的主要科研项目:河南大学特支计划第三层次,2018-2022,400万元。国家自然科学基金面上项目,2017-2020,64万元。河南省创新型科技团队,团队牵头人,可见光有机催化,2017-2020。河南大学杰出青年人才培育计划,2015-2018,300万元。河南省特聘教授,2015-2019,50万元。河南省高校创新团队支持计划,团队牵头人,2015-2018,100万元。教育部新世纪优秀人才支持计划,2012-2014,50万元。国家自然科学基金面上项目,2011-2013,36万元。河南省科技厅创新人才杰出青年,2011-2013,30万元。教育部留学归国人员启动基金,2011-2013,4万元。教育部高等学校博士学科点专项科研基金,2011-2013,3.6万元。河南省科技厅国际合作项目,2010-2012。河南大学黄河学者启动基金,2009-2012,50万元。获得荣誉与奖励:国务院政府特殊津贴(2018)国家百千万人才工程入选者(2017)国家“有突出贡献中青年专家”(2017)河南省科技进步二等奖(排名1,2017)开封市优秀教师(2017)河南省教育厅科技进步一等奖(排名1,2016)河南省第十七届青年五四奖章(2013)河南省学术技术带头人(2012)河南省第十一届青年科技奖(2012)河南省优秀青年科技专家称号(2012)河南省青少年科技创新奖(青年组)(2012)河南省教育厅学术技术带头人(2010)河南省青年骨干教师(2010)研究领域
1、不对称有机催化2、可见光不对称有机催化""近期论文
Li, F.; Tian, D.; Fan, Y.; Lee, R.; Lu, G.; Yin, Y.; Qiao, B.; Zhao, X.; Xiao, Z.; Jiang, Z.* Chiral Acid-Catalysed Enantioselective C−H Functionalization of Toluene and Its Derivatives Driven by Visible Light. Nat. Commun.2019, 10, 1774.Cao, K.; Tan, S. M.; Lee, R.; Yang, S.; Jia, H.; Zhao, X.; Qiao, B.; Jiang, Z.* Catalytic Enantioselective Addition of Prochiral Radicals to Vinylpyridines. J. Am. Chem. Soc.2019, 141, 5437−5443.Shao, T.; Li, Y.; Ma, N.; Li, C.; Chai, G.; Zhao, X.; Qiao, B.*; Jiang, Z.* Photoredox-Catalyzed Enantioselective α-Deuteration of Azaarenes with D2O. iScience2019, 16, 410−419.Hou, M.; Lin, L.; Chai, X.; Zhao, X.; Qiao, B.*; Jiang, Z.* Enantioselective Photoredox Dehalogenative Protonation. Chem. Sci.2019, 10, 6629−6634.Zhu, B.; Lu, B.; Zhang, H.; Xu, X.; Jiang, Z.*; Chang, J.* Phase-Transfer-Catalyzed, Enantioselective Vinylogous Conjugate Addition−Cyclization of Olefinic Azlactones To Access Multifunctionalized Chiral Cyclohexenones. Org. Lett.2019, 21, 3271−3275.Qiao, B.; Li, C.; Zhao, X.; Yin, Y.; Jiang, Z.* Enantioselective Reductive of Azaarene-Based Ketones via Visible Light-Driven Photoredox Asymmetric Catalysis. Chem. Commun.2019, 55, 7534−7537.Zeng, G.; Li, Y.; Qiao, B.; Zhao, X.*; Jiang, Z.* Photoredox Asymmetric Catalytic Enantioconvergent Substitution of 3-Chlorooxindoles. Chem. Commun.2019, DOI:10.1039/C9CC05304B.Liu, X.; Yin, Y.*; Jiang, Z.* Photoredox-Catalysed Formal [3+2] Cycloaddition of N-Aryl α-Amino Acids with Isoquinoline N-Oxides. Chem. Commun.2019, DOI:10.1039/C9CC06249A.Liu, Y.; Liu, X.; Li, J.; Zhao, X.; Qiao, B.; Jiang, Z.* Catalytic Enantioselective Radical Coupling of Activated Ketones with N-Aryl Glycines. Chem. Sci.2018, 9, 8094−8098.Liu, X.; Liu, Y.; Chai, G.; Qiao, B.; Zhao, X.; Jiang, Z.* Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines. Org. Lett.2018, 20, 6298−6301.Zhu, B.; Li, F.; Lu, B.; Chang, J.;* Jiang, Z.* Organocatalytic Enantioselective Vinylogous Aldol Reaction of 5-Alkyl-4-Nitroisoxazoles to Paraformaldehyde. J. Org. Chem.2018, 83, 11350−11358.Li, J.; Kong, M.; Qiao, B.; Lee, R.; Zhao, X.; Jiang, Z.* Catalytic Asymmetric Photoredox Radical Substitution Reactions of Alkyl Halides. Nat. Commun.2018, 9, 2445.Bu, L.; Li, J.; Yin, Y.; Qiao, B.; Chai, G.; Zhao, X.*; Jiang, Z.* Organocatalytic Asymmetric Cascade Aerobic Oxidation and Semipinacol Rearrangement Reaction: A Visible Light-Induced Approach to Access Chiral 2,2-Disubstituted Indolin-3-ones. Chem. Asian. J.2018, 13, 2382−2387. (Invited for the Special Issue of homogeneous catalysis)Qiao, B.; Jiang, Z.* Catalytic Photoreduction Induced by Visible Light. ChemPhotoChem2018, 2, 703−714. (Invited Minireview)Yin, Y.; Dai, Y.; Jia, H.; Li, J.; Bu, L.; Qiao, B.; Zhao, X.; Jiang, Z. Conjugate Addition−Enantioselective Protonation of N-Aryl Glycines to α-Branched 2-Vinylazaarenes via Cooperative Photoredox and Asymmetric Catalysis. J. Am. Chem. Soc.2018, 140, 6083−6087. (Selected as Spotlights by JACS and cover picture) (Highlighted by Synfactsof the month, 2018, 14, 0753; Contributors: Benjamin List, David Díaz-Oviedo)Shao, T.; Yin, Y.; Lee, R.; Zhao, X.; Chai, G.; Jiang, Z. Sequential Photoredox Catalysis for Cascade Aerobic Decarboxylative Povarov and Oxidative Dehydrogenation Reactions of N-Aryl α-Amino Acids. Adv. Synth. Catal.2018, 360, 1754−1760. (selected as the Very Important Publication and cover picture)Zhu, B.; Lee, R.; Yin, Y.; Li, F.; Coote, M. L.;* Jiang, Z.* Enantioselective Vinylogous Amination of 5-Alkyl-4-nitroisoxazoles with a Dipeptide-Based Guanidinium Phase-Transfer Catalyst. Org. Lett.2018, 20, 429−432.Li, S.; Zhu, B.; Lee, R.; Qiao, B.; Jiang, Z.* Visible Light-Induced Selective Aerobic Oxidative Transposition of Vinyl Halides Using a Tetrahalogenoferrate(III) Complex Catalyst. Org. Chem. Front.2018, 5, 380−385.Yin, Y.; Jiang, Z.* Organocatalytic Asymmetric Vinylogous Michael Reactions. ChemCatChem2017, 9, 4306−4318.Li, L.; Bai, X.; Ye, X.; Zhao, W.; Tan, C.-H. Jiang, Z.* Organocatalytic Enantioselective Protonation for Photoreduction of Activated Ketones and Ketimines Induced by Visible Light. Angew. Chem. Int. Ed.2017, 56, 13842−13846. (Highlighted by Synfacts2017, 13, 1318; Contributors: Benjamin List, Grigory A. Shevchenko)Hong, S.-N.; Liu, Y.; Lee, R.; Jiang, Z.* Asymmetric Tandem Conjugate Addition−Protonation to Forge Chiral Secondary C−O Bonds for Quaternary Carbon Stereocenters at the Nonadjacent β-Position. Chem. Commun.2017, 53, 7493−7496.Zhang, G.; Yin, Y.; Zhao, X.;* Jiang, Z.* Organocatalytic Asymmetric Tandem Conjugate Addition−Protonation of Azlactones to N-Itaconimides. Synlett2017, 28, 1310−1314. (Invited Cluster)Bai, X.; Zeng, G.; Shao, T.; Jiang, Z.* Catalytic Enantioselective γ-Selective Additions of 2-Allylazaarenes to Activated Ketones. Angew. Chem. Int. Ed.2017, 56, 3684−3688. (Highlighted by Synfacts2017, 13, 0544; Contributors: Benjamin List, Sebastian Schwengers)Liu, X.; Lin, L.; Ye, X.; Tan, C.-H.; Jiang Z.* Aerobic Oxidation of Benzylic sp3 C−H Bond through Cooperative Visible Light Photoredox Catalysis of N-Hydroxyimide and Dicyanopyrazine. Asian J. Org. Chem.2017, 6, 422−425. (Invited)Shao, T.; Jiang, Z.* Visible Light Mediated Photocatalytic Aerobic Dehydrogenation: A General and Direct Approach to Access 2,3-Dihydro-4-Pyridones and 4-Quinolones. Acta Chim. Sinica, 2017, 75, 70−73. (Invited)Li, J.; Qiu, S.; Ye, X.; Zhu, B.; Liu, H.; Jiang Z.* Dipeptide-Based Chiral Tertiary Amine-Catalyzed Asymmetric Conjugate Addition Reactions of 5H-Thiazol/Oxazol-4-Ones. J. Org. Chem.2016, 81, 11916−11923.Liu, Y.; Li, J.; Ye, X.; Zhao, X.; Jiang Z.* Organocatalytic Asymmetric Formal Arylation of Benzofuran-2(3H)-ones and Cooperative with Visible Light Photocatalysis. Chem. Commun.2016, 52, 13955−13958. (Selected as the cover picture)Qiu, S.; Tan, C.-H.;* Jiang Z.* Highly Chemo-, Enantio-, and Diastereo-selective [4+2] Cycloaddition of 5H-thiazol-4-ones with N-Itaconimides. Beilstein J. Org. Chem.2016, 12, 2293−2297. (Invited)Jiao, L.; Bu, L.; Ye, X.; Zhao, X.; Jiang, Z.* Catalytic Asymmetric Addition and Sulfenylation of Diarylthiazolidin-2,4-Diones. J. Org. Chem.2016, 81, 9620−9629.Zhang, C.; Li, S.; Bureš, F.; Lee, R.; Ye, X.; Jiang, Z.* Visible Light Photocatalytic Aerobic Oxygenation of Indoles and pH as a Chemoselective Switch. ACS Catal.2016, 6, 6853−6860.Qiu, S.; Lee, R.; Zhu, B.; Coote, M. L.; Zhao, X.;* Jiang, Z.* Highly Enantio- and Diastereoselective [4+2] cycloaddition of 5H-Oxazol-4-ones with N-Maleimides. J. Org. Chem.2016, 81, 8061−8069.Wei, G.; Basheer, C.; Tan, C.-H.; Jiang, Z.* Visible Light Photocatalysis in Chemoselective Functionalization of C(sp3)−H Bonds Enabled by Organic Dyes. Tetrahedron Lett.2016, 57, 3801−3809. (Invited Digest)Zhu, B.; Qiu, S.; Li, J.; Coote, M. L.; Lee, R.; Jiang, Z.* Asymmetric [4+2] Annulation of 5H-Thiazol-4-Ones with a Chiral Dipeptide-Based Brønsted Base Catalyst. Chem. Sci.2016, 6, 6060−6067.Hou, X.; Jing, Z.; Bai, X.; Jiang, Z.* A One-Pot Tandem Strategy in Catalytic Asymmetric Vinylogous Aldol Reaction of Homoallylic Alcohols. Molecules2016, 21, 842.Wei, G.; Zhang, C.; Burěs, F.; Ye, X.; Tan, C.-H.; Jiang, Z.* Enantioselective Aerobic Oxidative C(sp3)−H Olefination of Amines via Cooperative Photoredox and Asymmetric Catalysis. ACS Catal.2016, 6, 3708−3712.Jiao, L.; Zhao, X.; Liu, H.; Ye, X.; Li, Y.; Jiang, Z.* Organocatalytic Asymmetric Conjugate Addition of Diaryloxazolidin-2,4-diones to Nitroolefins: An Efficient Approach to Chiral α-Aryl-α-Hydroxy Carboxylic Acids. Org. Chem. Front.2016, 3, 470−474.Jing, Z.; Bai, X.; Chen, W.; Zhang, G.; Zhu, B.; Jiang, Z.* Organocatalytic Enantioselective Vinylogous Aldol Reaction of Allyl Ketones to Activated Acyclic Ketones. Org. Lett.2016, 18, 260−263.Zhu, B.; Lee, R.; Li, J.; Ye, X.; Hong, S.-N.; Qiu, S.; Coote, M. L.; Jiang, Z.*Turning Chemoselective Switch in Asymmetric Organocatalysis of 5H-oxazol-4-ones and N-Itaconimides towards Tandem Conjugate Addition−Protonation or [4+2] Cycloaddition, Angew. Chem. Int. Ed.2016, 55, 1299−1303.Bai, X.; Jing, Z.; Liu, Q.; Ye, X.; Zhang, G.; Zhao, X.; Jiang, Z.*L-Amino Acid-Based Urea−Tertiary Amine-Catalyzed Chemoselective and Asymmetric Stereoablative Carboxylation of 3-Bromooxindoles with Malonic Acid Half Thioesters, J. Org. Chem.2015, 80, 12686−12696.Huang, L.; Li, J.; Zhao, Y.; Ye, X.; Liu, Y.; Yan, L.; Tan, C.-H.; Liu, H.; Jiang, Z.* Chiral Bicyclic Guanidine-Catalyzed Enantioselective Sulfenylation of Oxindoles and Benzofuran-2(3H)-ones. J. Org. Chem.2015, 80, 8933−8941.Liu, X.; Ye, X.; Bureš, Liu, H.; Jiang, Z.* Controllable Chemoselectivity in Visible-Light Photoredox Catalysis: Four Diverse Aerobic Radical Cascade Reactions, Angew. Chem. Int. Ed.2015, 54, 11443−11447.Duan, S.; Li, S.; Ye, X.; Du, N.-N.; Tan, C.-H. Jiang, Z. Enantioselective Synthesis of Dialkylated α-Hydroxy Carboxylic Acids through Asymmetric Phase-Transfer Catalysis, J. Org. Chem.2015, 80, 7770−7778.Zhao, X.; Zhu, B.; Jiang, Z.* Acyclic Amino Acid-Based Bifunctional Chiral Tertiary Amines, Quaternary Ammoniums and Iminophosphoranes as Organocatalysts, Synlett, 2015, 26, 2216−2230. (Invited Account)Zhao, X.; Shen, J. Jiang, Z.* Catalytic Asymmetric α-Sulfenylation: A New and Efficient Pathway to Access Chiral C-S Bonds, Mini-Reviews in Organic Chemistry, 2014, 11, 424−431.Liu, Q.; Qiao, B.; Chin, K. F.; Tan, C.-H.; Jiang, Z.* Asymmetric Michael Addition of 5H-Oxazol-4-ones to Vinyl Sulfones: Highly Stereoselective Synthesis of Monofluorinated Analogs of 2-Tertiary Hydroxyl-3-Methyl-Substituted Carboxylic Acid Derivatives, Adv. Synth. Catal.2014, 356, 3777−3783.Xu, M.; Qiao, B.; Duan, S.; Liu, H.;* Jiang, Z.* Highly Enantioselective α-Sulfenylation of 5H-Oxazol-4-Ones to N-(Sulfanyl)Succinimides, Tetrahedron2014, 70, 8696−8702.Qiao, B.; Liu, X.; Duan, S.; Yan, L.; Jiang, Z.* Highly Enantioselective Organocatalysis α-Sulfenylation of Azlactones. Org. Lett.2014, 16, 672−675.Chen, W.; Jing, Z.; Chin, K. F.; Qiao, B.; Zhao, Y.; Yan, L.; Tan, C.-H.; Jiang, Z.* Catalytic Asymmetric Conjugate Addition of Mercaptans to β-Substituted-β-Trifluoromethyl Oxazolidinone Enoates: Access to Chiral Trifluoromethylated Tertiary Thioethers and Thiols, Adv. Synth. Catal.2014, 356, 1292−1300.Qiao, B.; Liu, Q.; Liu, H.; Yan, L.; Jiang, Z.* Asymmetric Decarboxylative 1,4-Addition of Malonic Acid Half Thioesters to Vinyl Sulfones: Highly Enantioselective Synthesis of 3-Monofluoromethyl-3-Arylpropanoic Esters, Chem. Asian. J.2014, 9, 1252−1256.Jing, Z.; Liu, J.; Chin, K. F.; Chen, W.; Tan, C.-H.; Jiang, Z.* Chiral Bicyclic Guanidine-Catalysed Conjugate Addition of α-Fluoro-β-Ketoesters to Cyclic Enones, Aust. J. Chem.2014, 67, 1119−1123. (Invited)Zhao, Y.; Zhang, C.; Chin, K. F.; Pytela, O.; Wei, G.; Liu, H.; Bureš, F.;* Jiang, Z.* Dicyanopyrazine-Derived Push-Pull Chromophores for Highly Efficient Photoredox Catalysis, RSC Adv.2014, 4, 30062−30067.Zhu, B.; Zhang, W.; Lee, R.; Han, Z.; Yang, W.; Tan, D.; Huang, K.-W.; Jiang, Z.*Direct Asymmetric Vinylogous Aldol Reaction of Allyl Ketones with Isatins: Divergent Synthesis of 3-Hydroxy-2-Oxindole Derivatives, Angew. Chem. Int. Ed.2013, 52, 6666–6670 (Selected as the inside back cover picture of Angewandte Chemie) (Highlighted by Synfacts2013, 9, 0784; Contributors: Benjamin List, Mattia Riccardo Monaco)Yang, C.; Chen, W.; Yang, W.; Zhu, B.; Yan, L.; Tan, C.-H.; Jiang, Z.* Bicyclic-Guanidine-Catalyzed Asymmetric Michael Addition of 3-Substituted Oxindoles to 2-Cyclopentenone, Chem. Asian J.2013, 8, 2960−2964.Chen, W.; Yang, W.; Yan, L.; Tan, C.-H.; Jiang, Z.* Bicyclic Guanidinium-Catalyzed Enantioselective Phase-Transfer Alkylation: Direct Access to Pyrroloindolines and Furoindolines, Chem. Commun.2013, 49, 9854−9856.Han, Z.; Yang, W.; Tan, C.-H.; Jiang, Z.* Organocatalytic Asymmetric Mannich Reactions of 5H-Oxazol-4-ones: Highly Enantio- and Diastereoselective Synthesis of Chiral α-Alkylisoserine Derivatives, Adv. Synth. Catal. 2013, 355, 1505–1511.Qiao, B.; An, Y.; Liu, Q.; Yang, W.; Liu, H.; Shen, J.; Yan, L.; Jiang, Z.* Organocatalytic Asymmetric Michael Addition of 5H-Oxazol-4-ones to Nitroolefins, Org. Lett.2013, 15, 2358–2361.Tong, G.; Zhu, B.; Lee, R.; Yang, W.; Tan, D.; Yang, C.; Han, Z.; Yan, L.; Huang, K.-W.; Jiang, Z.* Highly Enantio- and Diastereoselective Allylic Alkylation of Morita-Baylis-Hillman Carbonates with Allyl Ketones, J. Org. Chem.2013, 78, 5067–5072.Yan, L.; Han, Z.; Zhu, B.; Yang, C.; Tan, C.-H.; Jiang, Z.* Asymmetric Alylic Alkylation of Morita-Baylis-Hillman Carbonates with α-Fluoro-β-Keto Esters, Beilstein J. Org. Chem.2013, 9, 1853–1857.Yan, L.; Wu, X.; Liu, H.; Xie, L.; Jiang, Z.* Catalytic Asymmetric Synthesis of γ-Butenolides by Direct Vinylogous Reactions, Mini-Rev. Med. Chem.2013, 13, 845–853. (Invited review)Zhang, W.; Tan, D.; Lee, R.; Tong, G.; Chen, W.; Qi, B.; Huang, K.-W.; Tan, C.-H.; Jiang, Z.*Highly Enantio- and Diastereoselective Reactions of γ-Substituted Butenolides via Direct Vinylogous Conjugate Additions, Angew. Chem. Int. Ed.2012, 51, 10069–10073. (Highlighted by Synfacts2012, 8, 1253; Contributors: Benjamin List, Ji Hye Kim) (Highlighted by organic-chemistry.org; http://www.organicchemistry.org/Highlights/2013/22July.shtm)Han, Z.; Chen, W.; Dong, S.; Yang, C.; Liu, H.; Pan, Y.; Yan, L.; Jiang, Z.* Highly Enantioselective Organocatalytic Sulfenylation of 3-Aryloxindoles, Org. Lett.2012, 14, 4670–4673.Yang, Y.; Moinodeen, F.; Chin, W.; Ma, T.; Jiang, Z.; Tan, C.-H. Pentanidium–Catalyzed Enantioselective α-Hydroxylation of Oxindoles Using Molecular Oxygen, Org. Lett.2012, 14, 4762–4765.Yang, W.; Tan, D.; Li, L.; Han, Z.; Yan, L.; Huang, K.-W.; Tan, C.-H.; Jiang, Z.* Direct Asymmetric Allylic Alkenylation of N−Itaconimides with Morita−Baylis−Hillman Carbonates, J. Org. Chem.2012, 77, 66006607.Li, L.; Chen, W.; Yang, W.; Pan, Y.; Liu, H.; Tan, C.-H.; Jiang, Z.* Bicyclic Guanidine-Catalyzed Asymmetric Michael Additions of 3-Benzyl-Substituted Oxindoles to N-Maleimides, Chem. Commun.2012, 48, 51245126.Yang, W.; Tan, D.; Lee, R.; Li, L.; Pan, Y.; Huang, K.-W.; Tan, C.-H.; Jiang, Z.* Catalytic Diastereoselective Tandem Conjugate Addition-Ellimination Reaction of Morita-Baylis-Hillman C-Adducts via C-C Bond Cleavage, Chem. Asian J.2012, 7, 771777. (Top ten most accessed articles published in Chemistry-An Asian Journal in 2011 and 2012)Yan, L.; Zhao, F.; Gan, Y.; Zhao, J.; Jiang, Z.* Chemoselective Deprotection of Aryl tert-Butyldimethylsilyl Ethers Promoted by Phosphates, Synth. Commun.2012, 42, 285291.Zhao, F.; Zhang, W.; Yang, W.; Pan, Y.; Chen, W.; Liu, H.; Yan, L.; Tan, C.-H.; Jiang, Z.* Synthesis of Sulfur-Substituted α-Stereogenic Amides and Ketones: Highly Enantioselective Sulfa-Michael Additions of 1,4-Dicarbonyl But-2-enes, Adv. Synth. Catal.2011, 353, 26242630.Yang, W.; Wei, X.; Pan, Y.; Lee, R.; Zhu, B.; Liu, H.; Yan, L.; Huang, K.-W.; Jiang, Z.;* Tan, C.-H.* Highly Enantio- and Diastereoselective Synthesis of β-Methyl-γ- Monofluoromethyl-Substituted Alcohols, Chem. Eur. J.2011, 17, 80668070. (Very important, VIP paper)Zhu, B.; Yan, L.; Pan, Y.; Lee, R.; Liu, H.; Han, Z.; Huang, K.-W.; Tan. C.-H.;* Jiang, Z.* Lewis Base Catalyzed Enantioselective Allylic Hydroxylation of Morita-Baylis-Hillman Carbonates with Water, J. Org. Chem.2011, 76, 68946900.Zhao, Y.; Pan, Y.; Liu, H.; Yang, Y.; Jiang, Z.;* Tan, C.-H.* Fluorinated Aromatic Ketones as Nucleophiles in the Asymmetric Organocatalytic Formation of C-C and C-N bonds: a Facile Route to the Construction of Fluorinated Quaternary Stereogenic Centers, Chem. Eur. J.2011, 17, 35713574.Yan, L.; Yang, W.; Li, L.; Shen, Y.; Jiang, Z.* A One-Pot Green Synthesis of Alkylidenesuccinimides, Chin. J. Chem.2011, 29, 19061910.Wang, J.; Liu, H.; Fan, Y.; Yang, Y.; Jiang, Z.;* Tan, C.-H.* ‘Bicyclic Guanidine-Catalyzed Direct Asymmetric Allylic Addition of N-Aryl Alkylidene-Succinimides, Chem. Eur. J.2010, 16, 1253412537.Pan, Y.; Zhao, Y.; Ma, T.; Yang, Y.; Liu, H.; Jiang, Z.;* Tan, C.-H.* Enantioselective Synthesis of α-Fluorinated β-Amino Acid Derivatives by an Aymmetric Mannich Reaction and Selective Deacylation/Decarboxylation Reactions, Chem. Eur. J.2010, 16, 779782.Pan, Y.; Kee, C.-W.; Jiang, Z.; Ma, T.; Zhao, Y.; Yang, Y.; Xue, H.; Tan, C-.H.* Expanding the Utility of Brønsted Base Catalysis: Biomimetic Enantioselective Decarboxylative Reactions, Chem. Eur. J.2011, 17, 8363‒8370.Jiang, Z.; Pan, Y.; Zhao, Y.; Ma, T.; Lee, R.; Yang, Y.; Huang, K.-W.; Wong, M. W.;* Tan, C.-H.* Synthesis of Chiral Quaternary Carbon Center Bearing a Fluorine Atom: Enantio- and Diastereoselective Guanidine-Catalyzed Addition of Fluorocarbon Nucleophiles, Angew. Chem. Int. Ed. 2009, 48, 36273631. (Hot paper Chosen by Angewandte Chemie)Jiang, Z.; Yang, Y.; Pan, Y.; Zhao, Y.; Liu, H.; Tan, C.-H.* Synthesis of α-Stereogenic Amides and Ketones via Enantioselective Conjugate Addition of 1,4-Dicarbonyl But-2-Enes, Chem. Eur. J.2009, 15, 49254930.Jiang, Z.; Ye, W.; Yang, Y.; Tan, C.-H.* Rate Acceleration of Triethylamine-Mediated Guanidine-Catalyzed Enantioselective Michael Reaction, Adv. Synth. Catal.2008, 350, 23452351.Ye, W.; Jiang, Z.; Zhao, Y.; Goh, L. M. Serena; Leow, D.; Soh, Y.-T.; Tan, C.-H.* Chiral Bicyclic Guanidine as a Versatile Brønsted Base Catalyst for the Enantioselective Michael Reactions of Dithiomalonates and β-Keto Thioesters. Adv. Synth. Catal.2007, 349, 24542458.Jiang, Z.; Zhang, Y.; Ye, W.; Tan, C.-H.* P-C Bond Formation via Direct and Three-Component Conjuagate Addition Catalyzed by 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) Tetrahedron Lett.2007, 48, 5154.Jiang, Z.; Chan, W. H.;* Lee, W. M. A. Synthesis of Enantiopure Sulfinimines (Thiooxime S-Oxides) Catalyzed by Yb(OTf)3 from p-Toluenesulfinamide and Aldehydes in Mild Reaction Conditions. J. Org. Chem.2005, 70, 10811083.Jiang, Z.; Wang, Y.-G.* A Mild, Efficient and Selective Cleavage of Aryl tert-Butyldimethysilyl Ethers using KOH in Ethanol, Chem. Lett.2003, 32, 568569.Jiang, Z.; Wang, Y.-G.* A Mild, Efficient and Selective Deprotection of t-Butylmethylsilyl-Protected Phenols Using Cesium Carbonate, Tetrahedron Lett.2003, 44, 38593861.Fu, X.; Jiang, Z.; Tan, C.-H.* Bicyclic Guanidine-Catalyzed Enantioselective Phospha-Michael Reaction: Synthesis of Chiral β-Aminophosphine Oxides and β-Aminophosphines, Chem. Commun. 2007, 50585060.Cui, S.-L.; Jiang, Z.; Wang, Y.-G.* A General and Efficient Protocol for the Synthesis of Biaryl Ethers from Aryl Silyl Ethers using Cs2CO3, Synlett2004, 10, 18291831.Wang, Y.-G.;* Wu, X.; Jiang, Z. A Mild and Efficient Selective Tetrahydropyranylation of Primary Alcohols and Deprotection of THP Ethers of Phenols and Alcohols using PdCl2(CH3CN)2 as Catalyst, Tetrahedron Lett.2004, 45, 29732976.Hua, J.; Jiang, Z.; Wang, Y.-G.* An Efficient and Chemoselective Deprotection of tert-Butyldimethylsilyl Protected Alcohols using SnCl22H2O as Catalyst, Chin. Chem. Lett.2004, 15, 14301432.Zhao, D.; Ong, S.-W.; Yue, Z.; Jiang, Z.; Toh, Y.-C.; Khan, M.; Shi, J.; Tan, C.-H.; Chen, J.,* Yu, H.* Dendrimer Hydrazides as Multivalent Transient Inter-cellular Linkers, Biomaterials2008, 29, 36933702.Xu, J.; Fu, X.; Low, R.; Goh, Y.-P.; Jiang, Z.; Tan, C.-H.* Tandem Conjugate Addition-Elimination Reaction Promoted by Chiral Pyrrolidinyl Sulfonamides (CPS), Chem. Commun. 2008, 55265528. 相关热点
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