张霄
近期热点
资料介绍
个人简历
2020.04 - 至今 福建师范大学化学与材料学院,研究员\r2018.06 - 2020.03 中国科学院上海有机化学研究所金属有机国家重点实验室,副研究员\r2017.09 - 2018.05 中国科学院上海有机化学研究所金属有机国家重点实验室,助理研究员\r2015.09 - 2017.08 德国马尔堡大学,博士后,洪堡学者(合作导师:Eric Meggers 教授)\r2010.09 - 2015.07 中国科学院上海有机化学研究所金属有机国家重点实验室,博士(导师:游书力 研究员)\r2006.09 - 2010.07 安徽师范大学化学与材料科学学院,学士\r\r近期荣誉与获奖情况\r2020 福建省闽江学者特聘教授\r2019 中国科学院青年创新促进会会员\r2018 上海市青年科技英才扬帆计划\r2015-2017 德国亚历山大•冯•洪堡奖学金\r2015 杨念祖优秀博士生奖学金研究领域
"""""光化学合成,不对称催化"近期论文
Zhu, M.; Huang, X.-L.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-Light-Mediated Synthesis of Cyclobutene-Fused Indolizidines and Related Structural Analogs. CCS Chem. 2020, 2, Doi: 10.31635/ccschem.020.202000254.\r\rCheng, Y.-Z.; Zhao, Q.-R.; Zhang, X.*; You, S.-L.* Asymmetric Dearomatization of Indole Derivatives with N-Hydroxycarbamates Enabled by Photoredox Catalysis. Angew. Chem. Int. Ed. 2019, 58, 18069-18074.\r\rZhu, M.; Zheng, C.*; Zhang, X.*; You, S.-L.* Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives. J. Am. Chem. Soc. 2019, 141, 2636-2644.\r\rXu-Xu, Q.-F.; Liu, Q.-Q.; Zhang, X.*; You, S.-L.* Copper-Catalyzed Ring Opening of Benzofurans and Enantioselective Hydroamination Cascade. Angew. Chem. Int. Ed. 2018, 57, 15204-15208.\r\rTu, H.-F.#; Zhang, X.#; Zheng, C.; Zhu, M.; You, S.-L.* Enantioselective dearomative prenylation of indole derivatives. Nat. Catal. 2018, 1, 601-608. (Tu, H.-F. and Zhang, X. contribute equally) \r\rMa, J.#; Zhang, X. #; Huang, X.; Luo, S.; Meggers, E.* Preparation of Chiral-at-Metal Catalysts and their Use in Asymmetric Photoredox Chemistry. Nat. Protoc. 2018, 13, 605-632. (Ma, J. and Zhang, X. contribute equally)\r\rXu-Xu, Q.-F.; Zhang, X.*; You, S.-L.* Enantioselective Synthesis of 4‑Aminotetrahydroquinolines via 1,2-Reductive Dearomatization of Quinolines and Copper(I) HydrideCatalyzed Asymmetric Hydroamination. Org. Lett. 2019, 21, 5357-5362. \r\rBao, C.-C.; Zheng, D.-S.; Zhang, X.*; You, S.-L.* Iridium/N-Heterocyclic Carbene Complex-Catalyzed Intermolecular Allylic Alkylation Reaction. Organometallics 2018, 37, 4763-4772. (Bao, C.-C. and Zheng, D.-S. contribute equally)\r\rZhu, M.; Zhou, K.; Zhang, X.*; You, S.-L.* Visible-Light-Promoted Intramolecular Trifluoromethylative Dearomatization of Indole Derivatives via Intermolecular Charge Transfer. Org. Lett. 2018, 20, 4379-4383.\r\rCheng, Y.-Z.; Zhou, K.; Zhu, M.; Li, L.-A.-C.; Zhang, X.*; You, S.-L.* Visible-Light Promoted Intermolecular Oxidative Dearomatization of β-Naphthols with N-Hydroxycarbamates. Chem. Eur. J. 2018, 24, 12519-12523.\r\rCheng, Y.-Z.; Zhang, X.*; You, S.-L.* Visible light mediated photocatalysis as a new tool for catalytic asymmetric dearomatization (CADA) reactions. Sci. Bull. 2018, 63, 809-811.\r\rZhang, X.; You, S.-L.* Removing the Mask in Catalytic Asymmetric Diamination of Alkenes. Chem. 2017, 2, 917-919. \r\rZhang, X.; Yang, Z.-P.; Huang, L.; You, S.-L.* Highly Regio- and Enantioselective Synthesis of N-Substituted 2-pyridones via Ir-Catalyzed Intermolecular Asymmetric Allylic Amination. Angew. Chem. Int. Ed. 2015, 54, 1873-1876.\r\rZhang, X.; Liu, W.-B.; Tu, H.-F.; You, S.-L.* Ligand-Enabled Ir-Catalyzed Intermolecular Diastereoselective and Enantioselective Allylic Alkylation of 3-Substituted Indoles. Chem. Sci. 2015, 6, 4525-4529.\r\rZhang, X.; Han, L.; You, S.-L.* Ir-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Indoles. Chem. Sci. 2014, 5, 1059-1063.\r\rZhang, X.; Yang, Z.-P.; Liu, C.; You, S.-L.* Ru-Catalyzed Intermolecular Dearomatization Reaction of Indoles with Allylic Alcohols. Chem. Sci. 2013, 4, 3239-3243.\r\rZhang, X.; You, S.-L.* Asymmetric Allylic Substitutions Catalyzed by Iridium Complexes Derived from C(sp2)–H Activation of Chiral Ligands. Aldrichimica Acta. 2020, 53, 11-18.\r\rZhang, X., You, S.-L.; Science of Synthesis: Metal-Catalyzed Cyclization Reactions 1. (Volume Editors: Ma, S.; Gao, S.) Chapter 3. Metal-Catalyzed Intramolecular Allylic Substitution Reactions. 2016, 95-150.\r\rZhang, X.; You, S.-L.* THQphos in Ir-Catalyzed Asymmetric Allylic Substitution Reactions. Chimia 2018, 72, 589-594. (Invited paper for Homogeneous Catalysis – New Transformations and Mechanistic Insights Special Issue)\r\rZhang, X.; Qin, J.; Huang, X.; Meggers, E.* One-Pot Sequential Photoredox Chemistry and Asymmetric Transfer Hydrogenation with a Single Catalyst. Eur. J. Org. Chem. 2018, 2018, 571-577.\r\rZhang, X.; Qin, J.; Huang, X.; Meggers, E.* Sequential Asymmetric Hydrogenation and Photoredox Chemistry with a Single Catalyst. Org. Chem. Front. 2018, 5, 166-170. \r\rZhang, X.; Liu, W.-B.; Cheng, Q.; You, S.-L.* Iridium-Catalyzed Asymmetric Allylic Amination Reaction with N-Aryl Phosphoramidite Ligands. Organometallics 2016, 35, 2467-2472. \r\rZhang, X.; Wu, Q.-F.; Liu, W.-B.; You, S.-L.* Ruthenium-Catalyzed Intramolecular Allylic Dearomatization Reaction of Indole Derivatives Org. Lett. 2013, 15, 3746-3749.\r\rTang, S.-B.; Zhang, X.; Tu, H.-F.; You, S.-L.* Regio- and Enantioselective Rhodium-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with 1,3-Diketones. J. Am. Chem. Soc. 2018, 140, 7737-7742.\r\rLiu, W.-B.; Zhang, X.; Dai, L.-X.; You, S.-L.* Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of Indolines and Oxidation Strategy. Angew. Chem. Int. Ed. 2012, 51, 5183-5187.\r\rZhuo, C.-X.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of Pyrrole-Fused Piperazine and Piperazinone Derivatives via Ir-Catalyzed Asymmetric Allylic Amination. ACS Catal. 2016, 6, 5307-5310. \r\rXu-Xu, Q.-F.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of 4-Allyl Tetrahydroquinolines via Copper(I) Hydride-Catalyzed Hydroallylation of 1,2-Dihydroquinolines. Org. Lett. 2020, 22, 1530. \r\rTang, S.-B.; Tu, H.-F.; Zhang, X.; You, S.-L.* Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles. Org. Lett. 2019, 21, 6130-6134. \r\rShao, W.; Wang, Y.; Yang, Z.-P.; Zhang, X.; You, S.-L.* Efficient Synthesis of N-Alkylated 4-Pyridones by Copper-Catalyzed Intermolecular Asymmetric Propargylic Amination. Chem. Asian. J. 2018, 13, 1103-1107.\r\rLuo, S.; Zhang, X.; Zheng, Y.; Harms, K.; Zhang, L.; Meggers, E.* Enantioselective Alkynylation of Aromatic Aldehydes Catalyzed by a Sterically Highly Demanding Chiral-at-Rhodium Lewis Acid. J. Org. Chem. 2017, 82, 8995-9005.\r\rYe, K.-Y.; Zhang, X.; Dai, L.-X.; You, S.-L.* Ruthenium-Catalyzed Regioselective Allylic Trifluoromethylthiolation Reaction. J. Org. Chem. 2014, 79, 12106-12110. 相关热点