王铜道
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王铜道博士 特聘研究员,大连理工大学-化工与环境生命学部-张大煜学院2008和2013年分别获得厦门大学化学学士和有机化学博士学位(导师:夏海平教授),并均获评为当届的优秀毕业生。在厦门大学求学期间获得多项奖学金和荣誉称号,其中包括卢嘉锡奖学金(厦门大学化学化工学院三大奖之一)﹑博士研究生国家奖学金及入选厦门大学优秀博士培养计划等。博士毕业后,作为iChEM Fllow进入能源材料化学协同创新中心工作一年,随后于2014年至2017年在国际著名化学家Prof. Gerhard Erker课题组做博士后。目前以第一作者发表学术论文13篇,其中包括4篇Angew. Chem. Int. Ed.,2篇J. Am. Chem. Soc. 以及Chem. Sci. ﹑Sci. Rep.各一篇。2018年1月以特聘研究员A岗引进到张大煜学院工作。主要从事金属有机化学和元素有机化学方面的研究,研究内容包括:1)金属硼多重键的结构调控及反应性研究。2)金属硼受阻路易斯酸碱对化学。 教育经历Education Background 2008.92013.9厦门大学有机化学博士2004.92008.7厦门大学化学学士2001.92014.6安徽省明光中学理科工作经历Work Experience2017.12至今大连理工大学张大煜学院特聘研究员A岗2014.112017.12德国明斯特大学博士后2013.92014.8厦门大学能源材料化学协同创新中心博士后科研项目 锇硼烯的结构设计和反应性探索, 国家自然科学基金项目, 2018/08/16, 进行研究领域
1. 金属硼多重键的结构调控及反应性研究通过对金属中心配体和硼部分取代基的调控,设计合成结构新颖且稳定的金属硼双重键以及三重键化合物,并研究其反应性。通过对重要中间体的分离,深入研究反应机理,开拓新反应。2. 金属硼受阻路易斯酸碱对化学以构筑结构为基础,研究其与不饱和有机物﹑氢气﹑一氧化碳﹑二氧化碳,氧气和氮气等的反应性,并探索其作为催化剂在有机合成中的应用(比如催化氢化反应﹑硼基化反应﹑硅烷化反应及氢胺化反应等)。在金属有机化学和硼化学上发展新概念、新反应并深入研究这些新概念、新反应与材料科学、生物科学、能源科学等交叉融合。""近期论文
1. Tongdao Wang, Constantin G. Daniliuc, Christian Mueck-Lichtenfeld, Gerald Kehr, Gerhard Erker* Formation of Reactive p-Conjugated Frustrated N/B Pairs by Borane-Induced Propargyl Amine Rearrangement, J. Am. Chem. Soc. 2018, 140, 3635−3643.2. Tongdao Wang, Gerald Kehr, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerhard Erker* Selective Oxidation of an Active Intramolecular Amine/Borane Frustrated Lewis Pair with Dioxygen, J. Am. Chem. Soc. 2016, 138, 4302−4305.3. Tongdao Wang, Jun Zhu, Feifei Han, Chen Zhou, Hanyu Chen, Hong Zhang*, Haiping Xia* Synthesis of Five-membered Osmacycloallenes and Conversion into Six-membered Osmacycloallenes, Angew. Chem. Int. Ed. 2013, 52, 13361-13364.4. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization in an Osmabenzene System, Angew. Chem. Int. Ed. 2013, 52, 9251–9255. (+contributed equally)5. Tongdao Wang+, Hong Zhang+, Feifei Han, Ran Lin, Zhenyang Lin*, Haiping Xia* Synthesis and Characterization of a Metallapyridyne Complex, Angew. Chem. Int. Ed. 2012, 51(39): 9838-9841. (+contributed equally)6. Tongdao Wang, Shunhua Li, Hong Zhang, Ran Lin, Feifei Han, Yumei Lin, Ting Bin Wen, Haiping Xia* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48, 6453-6456.7. Tongdao Wang, Long Wang, Constantin G. Daniliuc, Kamil Samigullin, Matthias Wagner, Gerald Kehr, Gerhard Erker* CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template, Chem. Sci. 2017, 8, 2457-2463.8. Tongdao Wang, Feifei Han, Haiping Huang, Jinhua Li, Hong Zhang*, Jun Zhu, Zhenyang Lin*, Haiping Xia* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation, Sci. Rep. 2015, 5, 9584.9. Tongdao Wang, Gerald Kehr, Constantin G. Daniliuc, Gerhard Erker* Metal-Free Carbonylation Route to a Reactive Borataepoxide System, Organometallics 2018, 37, 1040-1049.10. Tongdao Wang+, Sonja Kohrt+, Constantin G. Daniliuc, Gerald Kehr and Gerhard Erker* Borata-Wittig olefination reactions of ketones, carboxylic esters and amides with bis(pentafluorophenyl)borata-alkene reagents Org. Biomol. Chem. 2017, 15, 6223-6232.(+contributed equally)11. Tongdao Wang, Xenia Jentgens, Constantin G. Daniliuc, Gerald Kehr, and Gerhard Erker* Tris(pentafluorophenyl)borane-Catalyzed Reaction of Phosphorus/Boron and Nitrogen/Boron Frustrated Lewis Pair Dihydrogen Activation Products with Alkenes and Alkynes, ChemCatChem 2017, 9, 651-658.12. Tongdao Wang, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker* Cyclic Amine/Borane Lewis Pairs by the Reaction of N,NDiallylaniline with Lancaster’s H2B-C6F5 Reagent, Chem. Asian J. 2016, 11, 1394–1399.13. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study, Chem. Eur. J. 2013, 19, 10982–10991. (+contributed equally)14. Shunxi Dong, Long Wang, Tongdao Wang, Constantin G. Daniliuc, Melanie Brinkkötter, Hellmut Eckert, Gerald Kehr, Gerhard Erker* Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems, Dalton Trans., 2018, DOI: 10.1039/c8dt00672e15. Lipeng Long, Xiaoxi Zhou, Tongdao Wang, Zhixin Chen, Hong Zhang,* Haiping Xia* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine, Organometallics 2017, 36, 4184−4190. 16. Feifei Han, Jinhua Li, Hong Zhang,* Tongdao Wang, Zhenyang Lin,* Haiping Xia* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene, Chem. Eur. J. 2015, 21, 565–567.17. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang*, Haiping Xia* A Novel m-Metallaphenol: Synthesis and Reactivity Studies, Chem. Eur. J. 2014, 20, 4363–4372.18. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang, Laiying Zhang, Xumin He*, Haiping Xia* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex, Organometallics 2014, 33, 5301−5307.19. Hong Zhang*, Ran Lin, Guangning Hong, Tongdao Wang, Ting Bin Wen, Haiping Xia* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes, Chem. Eur. J. 2010, 16, 6999-7007. 相关热点
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