个人简历

刘涛，教授，博士生导师，精细化工国家重点实验室副主任，主要从事分子磁性稳态可逆调控的研究，致力于解决分子层次上信息的写入、擦除与读取的问题，在Nat. Commun.、Angew. Chem. Int. Ed.、J. Am. Chem. Soc.、Chem. Sci.等期刊发表多篇论文。2013年获得国家自然科学基金委优秀青年基金，入选教育部新世纪优秀人才支持计划。2015年获得中国化学会青年化学奖，入选首批教育部青年长江学者。2018年入选国家“万人计划”青年拔尖人才。

研究领域

"""""物理刺激可逆控制电子转移及自旋转变\r
物理刺激调控分子磁性稳态\r
光、电、磁多功能耦合与协同响应\r
\r
面对分子层次上信息的写入、擦除与读取的挑战，围绕对应于二进制中0和1的磁性双稳态开展研究，主要的学术贡献如下：（1）利用激光诱导的双向自旋转变或电荷转移，发展了快速可逆操纵电子迁移与排布的策略，为磁性调控提供了光应答功能基元；（2）利用激光调控自旋态高低与磁耦合作用强弱，实现了作为信息载体的磁性双稳态的产生与消失的快速可逆控制，为单分子层次上信息的写入和擦除提供了方法；（3）利用激光诱导电子重排操纵自旋、电荷分布与能量转移，实现了磁、电、光多功能耦合与协同调控，为利用光、电信号跟踪磁性状态提供了平台。近年来在Nature Communications、Angew. Chem. Int. Ed.、J. Am. Chem. Soc.、Chem. Sci.等期刊发表45篇SCI论文，形成了富有特色的“分子磁性稳态可逆调控与多功能耦合”研究方向。"

近期论文

Manipulating Spin Transition To Achieve Switchable Multifunctions, ACCOUNTS OF CHEMICAL RESEARCH, 2019, 52, 1369-1379\r
Synergistic catalysis for light-driven proton reduction using a polyoxometalate-based Cu-Ni heterometallic-organic framework, CHEMICAL COMMUNICATIONS, 2019, 55, 3805-3808\r
Single-Molecule Magnet Behavior in Two Tetranuclear Cyanide-bridged (Fe2Ni2II)-Ni-III Compounds, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2019, 645, 428-432\r
Magnetic investigations over reversibly switched chiral (phthalocyaninato)(porphyrinato) dysprosium double-decker compounds, DALTON TRANSACTIONS, 2019, 48, 1586-1590\r
Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)2]2+ complexes, Dalton Transactions, 2019, 48, 6323-6327\r
Controlling magnetic exchange coupling via coligands in three cyanide-bridged heterobimetallic complexes, INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 97, 83-87\r
Manipulating Metal-to-Metal Charge Transfer for Materials with Switchable Functionality, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57, 12216-12226\r
Manipulation of successive crystalline transformations to control electron transfer and switchable functions, NATIONAL SCIENCE REVIEW, 2018, 5, 507-515\r
Syntheses, structures and magnetic properties of cyano-bridged (Fe2MII)-M-III (M = Mn, Co and Ni) one-dimensional chains, INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 93, 144-148\r
Controlling assembly and single-molecule magnet behavior of Fe-Ni clusters utilizing steric effect, INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 93, 87-91\r
Switching single chain magnet behavior via photoinduced bidirectional metal-to-metal charge transfer, CHEMICAL SCIENCE, 2018, 9, 617-622\r
Simultaneous Modulation of Magnetic and Dielectric Transition via Spin-Crossover Tuned Spin Arrangement and Charge Distribution., Angewandte Chemie (International ed. in English), 2018, 57, 8468-8472\r
Fluorescence modulation via photoinduced spin crossover switched energy transfer from fluorophores to FeII ions., Chemical science, 2018, 9, 2892-2897\r
Dual-Excitation Polyoxometalate-Based Frameworks for One-Pot Light-Driven Hydrogen Evolution and Oxidative Dehydrogenation., ACS applied materials & interfaces, 2018, 10, 13462-13469\r
Low-Coordinate Single-Ion Magnets by Intercalation of Lanthanides into a Phenol Matrix., Angewandte Chemie (International ed. in English), 2018, 57, 4673-4676\r
A Series of Linear {(Fe2FeII)-Fe-III} Complexes with Paramagnetic Building-Block-Modified Spin Crossover Behaviors, CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23, 15930-15936\r
A Material Showing Colossal Positive and Negative Volumetric Thermal Expansion with Hysteretic Magnetic Transition, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56, 13052-13055\r
Synergic on/off Photoswitching Spin State and Magnetic Coupling between Spin Crossover Centers, INORGANIC CHEMISTRY, 2017, 56, 10674-10680\r
Two-Step Spin-Crossover with Three Inequivalent Fe-II Sites in a Two-Dimensional Hofmann-Type Coordination Polymer, CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23, 10034-10037\r
Three Properties in One Coordination Complex: Chirality, Spin Crossover, and Dielectric Switching, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, 2017, 3144-3149\r
Light-Induced Bidirectional Metal-to-Metal Charge Transfer in a Linear Fe2Co Complex, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56, 7663-7668\r
Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56, 5465-5470\r
Sn-119 Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance, JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121, 6662-6673\r
Alkyne Activation by a Porous Silver Coordination Polymer for Heterogeneous Catalysis of Carbon Dioxide Cycloaddition, ACS CATALYSIS, 2017, 7, 2248-2256\r
Controllable antiferromagnetic to ferromagnetic coupling in polynuclear Fe(III)-Co(II) heterobimetallic complexes, INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 76, 55-58\r
光诱导的单链磁体性质及其研究进展, 中国科学. 化学, 2017, 47, 724-733\r
Single-molecule magnet behavior in a tetranuclear cyano-bridged (Fe2Ni2II)-Ni-III cluster, INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 74, 12-15\r
Magnetic fluorescent bifunctional spin-crossover complexes, DALTON TRANSACTIONS, 2016, 45, 18552-18558\r
氰基桥联的Fe(Ⅲ)-Mn(Ⅱ)双金属链的可控组装和磁性作用的调控, 无机化学学报, 2016, 32, 1637-1646\r
Coexistence of metamagnetism and single chain magnet behavior in a (Fe2CoII)-Co-III layer compound, SCIENCE CHINA-CHEMISTRY, 2016, 59, 735-739\r
Structural and Magnetic Properties of Fe-57-Doped TiO2 and Fe-57/Sn-Codoped TiO2 Prepared by a Soft-Chemical Process, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, , 2131-2135\r
Coexistence of the single chain magnet and spin-glass behavior in a cyano-bridged {(Fe2FeII)-Fe-III} chain, INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 66, 55-58\r
Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138, 3958-3961\r
Syntheses, structures, and magnetic properties of three new cyano-bridged heterobimetallic chains based on [Fe(Tp*)(CN)(3)](-), NEW JOURNAL OF CHEMISTRY, 2016, 40, 8451-8458\r
Spin transitions in a series of [Fe(pybox)(2)](2+) complexes modulated by ligand structures, counter anions, and solvents, INORGANIC CHEMISTRY FRONTIERS, 2016, 3, 1624-1636\r
Construction of solvent-dependent self-assembled porous Ni(II)-coordinated frameworks as effective catalysts for chemical transformation of CO2, RSC ADVANCES, 2016, 6, 108010-108016\r
Rational enhancement of the energy barrier of bis(tetrapyrrole) dysprosium SMMs via replacing atom of porphyrin core, CHEMICAL SCIENCE, 2015, 6, 5947-5954\r
周边硅笼取代的混杂酞菁卟啉三层铽单分子磁体, 无机化学学报, 2015, 31, 1761-1773\r
12-Metal 36-membered ring based W-V-Co-II layers showing spin-glass behavior, DALTON TRANSACTIONS, 2015, 44, 12613-12617\r
Charge Transfer Induced Multifunctional Transitions with Sensitive Pressure Manipulation in a Metal-Organic Framework, INORGANIC CHEMISTRY, 2015, 54, 6433-6438\r
Two cyano-bridged {(Fe4M2II)-M-III}c (M = Fe-II, Co-II) hexanuclear complexes with dominant ferromagnetic interactions, INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 57, 33-35\r
Two octacyanometallate based (WNiII)-Ni-V and (MoNiII)-Ni-V chains with dominant ferromagnetic interactions, INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 57, 29-32\r
Single-molecule magnet behavior in three cyano-bridged heterometallic Fe-III-Ni-II clusters, DALTON TRANSACTIONS, 2015, 44, 3393-3398\r
A cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions, DALTON TRANSACTIONS, 2015, 44, 464-467\r
A ferromagnetically coupled Fe-42 cyanide-bridged nanocage, Nature Communications, 2015, 6, 5955\r
Structural phase transition in a multi-induced mononuclear Fe-II spin-crossover complex, DALTON TRANSACTIONS, 2015, 44, 20906-20912\r
Mixed Tetrapyrrole Terbium Triplr-Decker Single Molecule Magnets with Bulky Inorganic Polyhedral Oligomeric Silsesquioxanes Moieties at Outer Porphyrin Peripheries, Chinese Journal of Inorganic, 2015, 31, 1761-1773\r
Two octacyanometallate based (WNiII)-Ni-V and (MoII)-Ni-V chains with dominant ferromagnetic interactions, Inorganic Chemistry Communications, 2015, 57, 29-32\r
Cyano-bridged Fe2Cu double-zigzag chains: From metamagnetism to coexistence of metamagnetism and single-chain magnet behavior, INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 49, 147-150\r
Cyano-bridged Fe2Cu clusters: Control of magnetic properties through cis-trans arrangement, INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 48, 8-11\r
From tetranuclear cluster with single-molecule-magnet behavior to 1D alternating spin-canting chain in a Fe(III)-Mn(III) bimetallic system, INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 47, 155-158\r
Enhanced Spin-Crossover Behavior Mediated by Supramolecular Cooperative Interactions, INORGANIC CHEMISTRY, 2014, 53, 8129-8135\r
Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2} complex with single crystal-to-single crystal transformation via intramolecular electron transfer, CHEMICAL COMMUNICATIONS, 2014, 50, 1665-1667\r
Cyanide bridged Fe2Cu clusters: control of magnetic properties through cis-trans arrangement, inorganic chemistry communications, 2014, 48, 8-11\r
Naphthyridine-based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5 '-monophosphate in vivo, TALANTA, 2013, 117, 412-418\r
Mixed (phthalocyaninato)(Schiff-base) di-dysprosium sandwich complexes. Effect of magnetic coupling on the SMM behavior, DALTON TRANSACTIONS, 2013, 42, 15355-15360\r
Field-induced slow relaxation of magnetization in a tetrahedral Co(II) complex with easy plane anisotropy, DALTON TRANSACTIONS, 2013, 42, 15326-15331\r
A near-infrared dye based on BODIPY for tracking morphology changes in mitochondria, CHEMICAL COMMUNICATIONS, 2013, 49, 10620-10622\r
A light-induced spin crossover actuated single-chain magnet, NATURE COMMUNICATIONS, 2013, 4, -\r
Binuclear Phthalocyanine-Based Sandwich-Type Rare Earth Complexes: Unprecedented Two -Bridged Biradical-Metal Integrated SMMs, CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19, 11162-11166\r
Slow magnetic relaxation in a cyano-bridged ferromagnetic {(FeNiII)-Ni-III} alternating chain, DALTON TRANSACTIONS, 2013, 42, 7693-7698\r
Synthesis, Structure, and Single-Molecule Magnetic Properties of Rare-Earth Sandwich Complexes with Mixed Phthalocyanine and Schiff Base Ligands, CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19, 2266-2270\r
A photoactive basket-like metal-organic tetragon worked as an enzymatic molecular flask for light driven H-2 production, CHEMICAL COMMUNICATIONS, 2013, 49, 627-629\r
Mixed (phthalocyaninato)(Schiff-base) di-dysprosium sandwich complex. Effect of magnetic coupling on the SMM behavior, DALTON TRANSATIONS, 2013, 42, 15355-15360\r
A Photoactive Basket-like Metal-organic Tetragon Worked as an Enzymatic Molecular Flask for Light Driven H2 Production, Chemical Communications, 2013, 49, 627-629\r
Naphthyridine based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5monophosphate in vivo, Talanta, 2013, 117, 412-418\r
Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III), JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134, 18487-18490\r
Mild hydrothermal synthesis, structure and characterization of the vanadyl phosphate hydrate Pb(VOPO4)(2)center dot 3H(2)O: the formation of spin dimers in a three dimensional crystal structure, JOURNAL OF MATERIALS CHEMISTRY, 2012, 22, 19872-19881\r
Synthesis, structures and single chain magnet behavior of a cyano-bridged {Fe2Cu} chain, INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 24, 153-156\r
A hexanuclear gadolinium-organic octahedron as a sensitive MRI contrast agent for selectively imaging glucosamine in aqueous media, CHEMICAL COMMUNICATIONS, 2012, 48, 9290-9292\r
Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag+ in aqueous solution, DALTON TRANSACTIONS, 2012, 41, 10153-10155\r
Synthesis, structures, electrochemistry and magnetic properties of a cyano-bridged {Fe2Co2} molecular square, INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 21, 84-87\r
Spin-canting and weak ferromagnetism in two novel 1D alternating chains with single cis-end-to-end azido bridges, SCIENCE CHINA-CHEMISTRY, 2012, 55, 1031-1036\r
Synthesis, structure, and magnetic properties of a cyanidebridged Fe(III)-Cu(II) bimetallic double-zigzag chain with slow relaxation of the magnetization, SCIENCE CHINA-CHEMISTRY, 2012, 55, 1018-1021\r
Tetrakis(phthalocyaninato) Rare-Earth-Cadmium-Rare-Earth Quadruple-Decker Sandwich SMMs: Suppression of QTM by Long-Distance f-f Interactions, CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18, 7691-7694\r
Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51, 5119-5123\r
Synthesis, crystal structure, and magnetic property of a rarely seen mu(1,1)-OMe-bridged dimeric manganese(III) complex derived from 2-[1-(2-methylaminoethylimino)ethyl]phenol, INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 19, 47-50\r
Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51, 4367-4370\r
Luminescent Metal-Organic Frameworks for Selectively Sensing Nitric Oxide in an Aqueous Solution and in Living Cells, ADVANCED FUNCTIONAL MATERIALS, 2012, 22, 1698-1703\r
Dual-Functional Gadolinium-Based Copper(II) Probe for Selective Magnetic Resonance Imaging and Fluorescence Sensing, INORGANIC CHEMISTRY, 2012, 51, 2325-2331\r