研究领域
金属有机化学 有机合成化学 不对称催化
近期论文
Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu and Gaosheng Yang*, “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination” Chem. Commun. 2014, 50, 177–179. Gaosheng Yang*, Yongxian Sun, Yue Shen, Zhuo Chai*, Shuangliu Zhou, Jiang Chu, and Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3 + 2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans” J. Org. Chem. 2013, 78, 5393–5400. Yongxian Sun, Gaosheng Yang*, Zhuo Chai*, Xiaolong Mu and Jun Chai, “AlCl3-promoted [3 + 2] annulation of cis-2,3-disubstituted cyclopropane 1,1-diesters with isothiocyanates: stereoselective synthesis of densely substituted 2-iminodihydrothiophenes” Org. Biomol. Chem. 2013, 11, 7859–7868. Yongxian Sun, Gaosheng Yang*, Yue Shen, Zan Hua, Zhuo Chai*, “Stereoselective cyclopropanation of a-bromochalcone with diethyl malonate promoted by K2CO3” Tetrahedron 2013, 69, 2733–2739. Gaosheng Yang*, Chongrong Luo, Xiaolong Mu, Tingting Wang and Xin-Yuan Liu*, “Highly Efficient Enantioselective Three-Component Synthesis of 2-Amino-4H-Chromenes Catalysed by Chiral Tertiary Amine-Thioureas” Chem. Commun. 2012, 48, 5880–5882. Gaosheng Yang*, Yue Shen, Kui Li, Yongxian Sun, Yuanyuan Hua, “AlCl3-Promoted Highly Regio- and Diastereoselective [3+2]Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans” J. Org. Chem. 2011, 76, 229–233. (This work has been highlighted in Synfacts) 骆崇荣, 陈楠楠, 华德智, 杨高升*, “苯磺酰硫脲衍生物的无溶剂合成” 有机化学, 2011, 31, 2167–2172. Gaosheng Yang*, Yuanyuan Hua, Yue, Shen, “K2CO3-Promoted Cascade Michael-Alkylation Reactions: A Facile Preparation of Diethyl trans-2,3-Disubstituted 1,1-Cyclopropanedicarboxylates” Chinese Journal of Chemistry, 2009, 27, 1811–1819. Xiaosheng Wang, Changwu Zheng, Shengli Zhao, Zhuo Chai, Gang Zhao*, Gaosheng Yang*, “Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with b,c-unsaturated a-keto ester to form novel optically active naphthopyran derivatives” Tetrahedron: Asymmetry,2008, 19, 2699–2704. Xiaosheng Wang, Gaosheng Yang*, and Gang Zhao*, “Enantioselective synthesis of naphthopyran derivatives catalyzed by bifunctional thiourea-tertiary amines” Tetrahedron: Asymmetry, 2008, 19, 709–714. 吴红伟, 杨高升*, “a-卤代酮与芳香二胺经氧化–缩合过程一锅法合成喹喔啉衍生物” 有机化学, 2008, 28, 2132–2136. Gaosheng Yang, Huiwei Tang, Yizhi Li, Jing Hong, Zijian Guo, Longgen Zhu*, “Syntheses, structures, and properties of two dinuclear palladium (II) complexes of a single macrocyclic hexaaza ligand with two hydroxyethyl pendants”, Inorganic Chemistry Communications, 2005, 8, 862–865. Gaosheng Yang, Ren Miao, Yizhi LI, Chen Jin, Jin Hong, Zijian Guo, Longgen Zhu*, “Self-inclusion of a New Calix[4]arene Derivative via Associated Acetonitrile: X-ray Diffraction and Density Functional Theory Studies” Chinese Journal of Chemistry, 2005, 23, 852–856. Gaosheng Yang,Ren Miao,Yizhi Li,Jing Hong,Chuenmei Zhao,Zijian Guoand Longgen Zhu*, “Synergic effect of two metal centers in catalytic hydrolysis of methionine-containing peptides promoted by dinuclear palladium(II) hexaazacyclooctadecane complex” Dalton Transactions, 2005, 1613–1619. Gaosheng Yang, Ren Miao, Chen Jin, Yuhua Mei, Huiwei Tang, Jin Hong, Zijian Guo and Longgen Zhu*, “Determination of binding sites in carboplatin-bound cytochrome c using electrospray ionization mass spectrometry and tandem mass spectrometry” Journal of Mass Spectrometry,2005, 40, 1005–1016. Gaosheng Yang, Chen Jin, Yizhi Li, Jing Hong, Ren Miao, Chuenmei Zhao, Zijian Guo and Longgen Zhu*, “Conformations and Structures of Two Novel Upper Rim Disubstituted Derivatives of Tetra-O-alkylcalix[4]arene: The Effect of Substituents” Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2005, 52, 119–127. Gaosheng Yang, Chen Jin, Jing Hong, Zijian Guo, Longgen Zhu*, “Ab initio and density functional theory studies on vibrational spectra of palladium (II) and platinum (II) complexes of methionine and histidine: effect of theoretical methods and basis sets” Spectrochimica Acta Part A, 2004, 60, 3187–3195. Gaosheng Yang, Jian-Bing Hu, Gang Zhao*, Yu Ding and Min-Hua Tang, “Catalytic enantioselective borane reduction of aromatic ketones with sulfonyl (S)-prolinol” Tetrahedron: Asymmetry, 1999, 10, 4307–4311. Gaosheng Yang, Xiao-juan Xie, Gang Zhao, Yu Ding*, “Palladium catalyzed cross-coupling reaction of organoboronic acids with beta-(perfluoroalkyl)ethyl iodides”, Journal of Fluorine Chemistry, 1999, 98, 159–161.
