个人简介
教育经历(Education)1999年9月–2003年7月 安徽师范大学化学专业 理学学士2003年9月–2008年7月 中国科学院上海有机化学研究所 有机化学专业 理学博士工作经历(Research experience)2008年–2009年 中国科学院上海有机化学研究所助理研究员2009年–2011年 Montana State University (USA) 博士后2011年–2012年 Université de Rouen et INSA de Rouen (France) 博士后2012年至今 安徽师范大学化学与材料科学学院 讲师,副教授,教授(2017年7月起)
研究领域
不对称催化,有机合成
近期论文
Pei-Jun Yang, Ling Qi, Zhen Liu, Gaosheng Yang, Zhuo Chai,* “Lewis Acid-Catalyzed Dynamic Kinetic Asymmetric Transformation of Racemic N-Sulfonylaziridines”, J. Am. Chem. Soc. 2018, 140, 17211–17217.Zhuo Chai, Yemei Wang, Mujun Tang, Xiaolong Mu, Jinsong Hou, Gaosheng Yang,* “Chiral rare-earth metal complexes with a tridentate amido-fluorenyl ligand: Syntheses, structures and catalytic performance”, J. Organomet. Chem. 2017,846, 236–241. Deju Hua, Pengfei Yang, Yue Shen, Gaosheng Yang,* Zhuo Chai,* “PCl5-mediated ring-openings of trans-2,3-disubstituted cyclopropane-1,1-diesters: a stereoselective way to trisubstituted vinyl cholorides”, Tetrahedron 2017, 73, 1205–1210.Zhuo Chai, Jiang Chu, Yunyi Qi, Mujun Tang, Jinsong Hou and Gaosheng Yang,* “Half-sandwich chiral rare-earth metal complexes with linked tridentate amido-indenyl ligand: synthesis, characterization, and catalytic properties for intramolecular hydroamination”, RSC Adv., 2017, 7, 1759–1765.Zhuo Chai,* Pei-Jun Yang, Hu Zhang, Shaowu Wang, Gaosheng Yang, “Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis ofN-Tosylaziridines”, Angew. Chem. Int. Ed. 2017, 56, 650–654 (highlighted in Synfacts, 2017, 396).Zhuo Chai,* Jia-Nan Chen, Zhen Liu, Xue-Fei Li, Pei-Jun Yang, Ji-Ping Hu, Gaosheng Yang, “[3+2]-Annulations of N-alkyl-3-substituted indoles with quinone monoketals catalysed by Br?nsted acids”, Org. Biomol. Chem. 2016, 14, 1024–1030.Zhuo Chai,* You-Min Zhu, Pei-Jun Yang, Shaoyin Wang, Shaowu Wang,* Zhen Liu, Gaosheng Yang, “Copper(I)-Catalyzed Kinetic Resolution of N-Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines”, J. Am. Chem. Soc. 2015, 137, 10088–10091 (highlighted by X-MOL: http://www.x-mol.com/news/5199).Gaosheng Yang,* Tingting Wang, Jun Chai, Zhuo Chai,* “AlCl3-Catalyzed [3+2] Annulations of cis-2,3-Disubstituted Cyclopropane 1,1-Diesters with Cyclic Ketones: Diastereoselective Construction of Spirotetrahydrofurans”, Eur. J. Org. Chem. 2015, 1040–1046.Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu, Gaosheng Yang,* “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination”, Chem. Commun. 2014, 50, 177–179.Zhuo Chai,* Biao Wang, Jia-Nan Chen, Gaosheng Yang, “Arylation of Azlactones using Diaryliodonium Bromides and Silver Carbonate: Facile Access to alpha-Tetrasubstituted Amino Acid Derivatives”, Adv. Synth. Catal. 2014,356, 2714–2718.Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu, Gaosheng Yang,* “Rare-earth metal complexes with tridentate linked amido-indenyl ligand: Synthesis, characterization, and catalytic properties for intramolecular hydroamination”, J. Organomet. Chem. 2014, 768, 136–139.Shaoyin Wang, Xiancui Zhu, Zhuo Chai,* and Shaowu Wang,* “Synthesis of polysubstituted pyrroles via [3+2]-annulation of aziridines and beta-nitroalkenes under aerobic conditions”, Org. Biomol. Chem. 2014, 12, 1351–1356. Yongxian Sun, Gaosheng Yang,* Zhuo Chai,* Xiaolong Mu, Jun Chai, “AlCl3-promoted [3+2] annulation of cis-2,3-disubstituted cyclopropane 1,1-diesters with isothiocyanates: stereoselective synthesis of densely substituted 2-iminodihydrothiophenes”, Org. Biomol. Chem. 2013, 11, 7859–7868.Yongxian Sun, Gaosheng Yang,* Yue Shen, Hua Zan, Zhuo Chai,* “Stereoselective cyclopropanation of a-bromochalcone with diethyl malonate promoted by K2CO3”, Tetrahedron 2013, 69, 5104–5111.Gaosheng Yang,* Yongxian Sun, Yue Shen, Zhuo Chai,* Shuangliu Zhou, Jiang Chu, Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3+2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans”, J. Org. Chem. 2013, 78, 5393–5400.Zhuo Chai, Jean-Philippe Bouillon, Dominique Cahard,* “Chiral Br?nsted Acid-Catalyzed Diastereo- and Enantioselective Synthesis of CF3-Substituted Aziridines”, Chem. Commun. 2012, 48, 9471–9473.Zhuo Chai, Trevor J. Rainey,* “Pd(II)/Br?nsted Acid Catalyzed Enantioselective Allylic C-H Activation for the Synthesis of Spirocyclic Rings”,J. Am. Chem. Soc. 2012, 134, 3615–3618.Zhuo Chai, Gang Zhao,* “Efficient Organocatalysts Derived From Simple Chiral Acyclic Amino Acids in Asymmetric Synthesis” Catal. Sci. Technol. 2012, 2, 29–41.Zhuo Chai, Hai-Feng Wang, Gang Zhao,* “Ni-Catalyzed Carbocyclization of 1,6-Enynes Mediated by Dialkylzinc Reagents: Me2Zn or Et2Zn Makes a Difference”, Synlett 2009, 1785–1790.Zhuo Chai, Zheng-Feng Xie, Xin-Yuan Liu, Ji-De Wang*, Gang Zhao*, “Tandem Addition/Cyclization Reaction of Organozinc Reagents to 2-Alkynyl Aldehydes: Highly Efficient Regio- and Enantioselective Synthesis of 1,3-Dihydroisobenzofurans and Tetrasubstituted Furans”, J. Org. Chem. 2008, 73, 2947–2950 (highlighted in Synfacts, 2008, 712).