个人简介

李亚辉，博士，青年皖江学者，博士生导师毕业于德国莱布尼茨催化研究所LIKAT，2018年8月作为海外高层次引进人才受聘于安徽农业大学资源与环境学院，安徽省农产品质量安全重点实验室，花日茂教授团队，实验室条件优越，经费充足。真诚欢迎各位同学报考本课题组研究生，补助及福利待遇除按学校有关规定执行外，将根据研究进展和贡献给予相应补贴。同时，对努力，优秀的学生，可推荐到国外及国内985高校攻读博士学位。同时欢迎对科研感兴趣的本科生加入到本课题组，对于努力，上进的学生，同样十分乐意帮助推荐到国外及国内985高校继续学习。实验条件：课题组配有专业从事有机合成实验室，岛津GC-MS2010气相色谱质谱联用仪，岛津GC-2010Pro气相色谱仪等设备。团队另配有总价值超2000万的先进测试设备如WatersXevoTQMS液质-质联用仪(2台)、Agilent7000C三重四极杆气质-质联用仪、Agilent6890GC、岛津气相色谱仪、Aglient1200HPLC、岛津LC-20AT液相色谱仪等

研究领域

新型农药研发，手性农药合成，羰基化在农药合成中应用

1）新型靶向农药的研发2）新型手性农药的合成3）小分子气体在农药合成中的应用4）有机合成

近期论文

Y. Li, X-F. Wu, Copper/Iron-Cocatalyzed Alkoxycarbonylation of Unactivated Alkyl Bromides, Communication Chemistry. DOI:10.1038/s42004-018-0039-6 Y. Li, YY. H, X.-F. Wu, Non-noble metal-catalysedcarbonylative transformations，Chem. Soc. Rev. 2018, 47, 172-194. IF > 40.1 Y. Li, Z.Wang, X.-F. Wu, Palladium-Catalyzed Carbonylative Direct Transformation of Benzyl Amines under Additive-Free Conditions, ACS Catal., 2018, 738–741. IF>11.3 Y. Li, K. Dong, F. Zhu, Z. Wang, X.-F. Wu，Copper-Catalyzed Carbonylative Coupling of Cycloalkanes and Amides，Angew. Chem. Int. Ed.,2016, 55, 7227-7230. (VIP Paper, Hightlighton Chemistryviews.org)，IF>12.1 Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Copper-Catalyzed Carbonylative Synthesis of Aliphatic Amides from Alkanes and Primary Amines via C(sp3)−H Bond Activation, ACS Catal., 2016, 5561-5564. IF>11.3 Y. Li, Z. Wang, X.-F. Wu, A Sustainable Procedure toward Alkyl Arylacetates: Palladium- Catalysed Direct Carbonylation of Benzyl Alcohols in Organic Carbonates, Green Chem.,2018, 20, 969-972. IF>8.5 Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Copper-Catalyzed Carbonylative Four Components Reaction of Ethene and Aliphatic Olefins, Chem. Commun., 2018, 54, 1984-1987. IF>6.3 Y. Li, C. Wang, F. Zhu, Z. Wang, P. H. Dixneuf, X.-F. Wu, Copper-Catalyzed Alkoxycarbonylation of Alkanes with Alcohols，ChemSusChem.，2017, 10, 1341-1345. (Back cover, VIP Paper), IF>7.4 Y. Li, C. Wang, F. Zhu, Z. Wang, J. Francois Soule, P. H. Dixneuf, X.-F. Wu, An unexpected copper-catalyzed carbonylative acetylation of amines，Chem. Commun., 2017, 53, 142-144. IF>6.3 Y Li, W. Liu, C. Kuang, Direct arylation of pyridines without the use of a transition metal catalyst, Chem. Comm., 2014, 50, 7124-7127. IF>6.3 Y. Li, F. Zhu, Z. Wang, J. Rabeah, A. Brückner, X.-F. Wu, Practical and General Manganese-Catalyzed Carbonylative Coupling of Alkyl Iodides with Amides. ChemCatChem., 2017, 9, 915-919. IF>4.8 Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal-Free Conditions. Chem. Asian J., 2016, 11,3503 –3507. IF>4.6 F. Zhu, Y. Li, Z. Wang, X. F. Wu, Iridium-Catalyzed Carbonylative Synthesis of Chromenones from Simple Phenols and Internal Alkynes at Atmospheric Pressure. Angew. Chem. Int. Ed. 2016, 55, 14151-14154. IF>11.9 Z. Wang, Y. Li, F. Zhu, X. F. Wu, Palladium-Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source. Adv. Synth. Catal. 2016, 358, 2855-2859，（IF>6.4） F. Zhu, Y. Li, Z. Wang, X. F. Wu, Iridium-Catalyzed Carbonylative Synthesis of Halogen-Containing Quinolin-2(1H)-ones from Internal Alkynes and Simple Anilines, Adv. Synth. Catal. ,2016, 358, 3350-3354, （IF>6.4） W. Liu, Y. Li, Y. Wang, C. Kuang. Pd-Catalyzed Oxidative CH/CH Direct Coupling of Heterocyclic N-Oxides, Org. Lett. , 2013, 18, 4682-4685, IF>6.5 W. Liu, Y. Li, B. Xu, C. Kuang. Palladium-Catalyzed Olefination and Arylation of 2-Substituted 1,2,3-Triazole N-Oxides, Org. Lett. 2013, 10, 2342 -2345. IF>6.5 F. Zhu, Y. Li, Z. Wang, R. V. Orru, B. U. Maes, X. F. Wu, Palladium-Catalyzed Construction of Amidines from Arylboronic Acids under Oxidative Conditions, Chem. Eur. J. 2016, 22, 7743-7746(Hot Paper). （IF>5.7） F. Zhu, Y. Li, Z. Wang, X.-F. Wu, Highly efficient synthesis of flavones via Pd/C-catalyzed cyclocarbonylation of 2-iodophenol with terminal acetylenes, Catal. Sci. Technol, 2016, 6, 2905-2909. （IF>5.7） F. Zhu, Y. Li, Z. Wang, X. F. Wu, An Efficient Rhodium-Catalyzed Carbonylative Annulation of Internal Alkynes and Anilines To Produce Maleimides, ChemCatChem, 2016, 8, 3710-3713. （IF>4.8）